[(η5-pentamethylcyclopentadienyl)2Ti(CC(C6H5))2Li(THF)2]

Base Information

Chemical Name:[(η5-pentamethylcyclopentadienyl)2Ti(CC(C6H5))2Li(THF)2]
CAS No.:390432-36-7
Molecular Formula:C₄₄H₅₆LiO₂Ti
Molecular Weight:671.748
Hs Code.:

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Chemical Property of [(η5-pentamethylcyclopentadienyl)2Ti(CC(C6H5))2Li(THF)2]

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Technology Process of [(η5-pentamethylcyclopentadienyl)2Ti(CC(C6H5))2Li(THF)2]

There total 1 articles about [(η5-pentamethylcyclopentadienyl)2Ti(CC(C6H5))2Li(THF)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

: 109-99-9,24979-97-3,77392-70-2
tetrahydrofuran

: 109-72-8,29786-93-4
n-butyllithium

: [(η5-pentamethylcyclopentadienyl)2TiCl]

: 536-74-3
phenylacetylene

: 390432-36-7
[(η5-pentamethylcyclopentadienyl)2Ti(CC(C6H5))2Li(THF)2]

Guidance literature:: In tetrahydrofuran; hexane; byproducts: LiCl; under Ar; a soln. of phenylacetylene in THF was cooled to -78°C and treated with a soln. of n-butyllithium in n-hexane, after 15 min the soln. was warmed to 25°C, (C5(CH3)5)2TiCl was added, the soln. was stirred for 24 h; the solvent was removed in vac., the residue was suspended in n-hexane, the mixt. was filtered, crystd. at -78°C, ppt. was filtered and dried in vac.; elem. anal.;
DOI:10.1021/om010404f

Reference yield: 32.0%

: 390432-36-7
[(η5-pentamethylcyclopentadienyl)2Ti(CC(C6H5))2Li(THF)2]

: 390432-39-0
[(η5-pentamethylcyclopentadienyl)2Ti(CC(C6H5))2]

Guidance literature:: With CO₂; In tetrahydrofuran; byproducts: C4H8O; under Ar; the complex was dissolved in THF, the soln. was stirred for 3 h at 25°C under an atm. of CO2; the C4H8O was evapd in vac., the residue was extd. with n-hexane, crystals were obtain by cooling the mixt. at -40°C for 48 h;
DOI:10.1021/om010404f