3-(4-bromo-2-chloro-6-methoxyphenyl)bicyclo[3.2.1]octane-2,4-dione

Base Information

Chemical Name:3-(4-bromo-2-chloro-6-methoxyphenyl)bicyclo[3.2.1]octane-2,4-dione
CAS No.:1615201-91-6
Molecular Formula:C₁₈H₁₇ClO₃
Molecular Weight:316.784
Hs Code.:

Synonyms:

Suppliers and Price of 3-(4-bromo-2-chloro-6-methoxyphenyl)bicyclo[3.2.1]octane-2,4-dione

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 3-(4-bromo-2-chloro-6-methoxyphenyl)bicyclo[3.2.1]octane-2,4-dione

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 3-(4-bromo-2-chloro-6-methoxyphenyl)bicyclo[3.2.1]octane-2,4-dione

There total 7 articles about 3-(4-bromo-2-chloro-6-methoxyphenyl)bicyclo[3.2.1]octane-2,4-dione which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 497-38-1
Norbornan-2-on

: 1615201-91-6
3-(4-bromo-2-chloro-6-methoxyphenyl)bicyclo[3.2.1]octane-2,4-dione

Guidance literature:: Multi-step reaction with 7 steps

1: potassium hydroxide / ethanol / 19 h / 85 °C / Inert atmosphere

2: dihydrogen peroxide; selenium(IV) oxide / water; tert-butyl alcohol / 48 h / 20 °C

3: eatons reagent / toluene / 1 h / 70 °C / Inert atmosphere

4: potassium carbonate / acetone / 22 h / 20 °C

5: (1,5-cyclooctadiene)(methoxy)iridium(I) dimer; 4,4'-di-tert-butyl-2,2'-bipyridine / tert-butyl methyl ether / 4 h / 80 °C / Inert atmosphere

6: copper(ll) bromide / methanol; water / 1 h / 80 °C / Inert atmosphere

7: bis-triphenylphosphine-palladium(II) chloride; 1,4-di(diphenylphosphino)-butane; tetrabutyl ammonium fluoride / dimethyl sulfoxide; tetrahydrofuran / 1 h / 110 °C / Inert atmosphere

With selenium(IV) oxide; bis-triphenylphosphine-palladium(II) chloride; (1,5-cyclooctadiene)(methoxy)iridium(I) dimer; eatons reagent; tetrabutyl ammonium fluoride; dihydrogen peroxide; potassium carbonate; 1,4-di(diphenylphosphino)-butane; 4,4'-di-tert-butyl-2,2'-bipyridine; potassium hydroxide; copper(ll) bromide; In tetrahydrofuran; methanol; ethanol; tert-butyl methyl ether; water; dimethyl sulfoxide; acetone; toluene; tert-butyl alcohol;

Reference yield:

: 29866-54-4
2-chloro-6-methoxybenzaldehyde

: 1615201-91-6
3-(4-bromo-2-chloro-6-methoxyphenyl)bicyclo[3.2.1]octane-2,4-dione

Guidance literature:: Multi-step reaction with 7 steps

1: potassium hydroxide / ethanol / 19 h / 85 °C / Inert atmosphere

2: dihydrogen peroxide; selenium(IV) oxide / water; tert-butyl alcohol / 48 h / 20 °C

3: eatons reagent / toluene / 1 h / 70 °C / Inert atmosphere

4: potassium carbonate / acetone / 22 h / 20 °C

5: (1,5-cyclooctadiene)(methoxy)iridium(I) dimer; 4,4'-di-tert-butyl-2,2'-bipyridine / tert-butyl methyl ether / 4 h / 80 °C / Inert atmosphere

6: copper(ll) bromide / methanol; water / 1 h / 80 °C / Inert atmosphere

7: bis-triphenylphosphine-palladium(II) chloride; 1,4-di(diphenylphosphino)-butane; tetrabutyl ammonium fluoride / dimethyl sulfoxide; tetrahydrofuran / 1 h / 110 °C / Inert atmosphere

With selenium(IV) oxide; bis-triphenylphosphine-palladium(II) chloride; (1,5-cyclooctadiene)(methoxy)iridium(I) dimer; eatons reagent; tetrabutyl ammonium fluoride; dihydrogen peroxide; potassium carbonate; 1,4-di(diphenylphosphino)-butane; 4,4'-di-tert-butyl-2,2'-bipyridine; potassium hydroxide; copper(ll) bromide; In tetrahydrofuran; methanol; ethanol; tert-butyl methyl ether; water; dimethyl sulfoxide; acetone; toluene; tert-butyl alcohol;

Reference yield:

: 1615211-82-9
(3E)-3-[(2-chloro-6-methoxyphenyl)methylene]norbornan-2-one

: 1615201-91-6
3-(4-bromo-2-chloro-6-methoxyphenyl)bicyclo[3.2.1]octane-2,4-dione

Guidance literature:: Multi-step reaction with 6 steps

1: dihydrogen peroxide; selenium(IV) oxide / water; tert-butyl alcohol / 48 h / 20 °C

2: eatons reagent / toluene / 1 h / 70 °C / Inert atmosphere

3: potassium carbonate / acetone / 22 h / 20 °C

4: (1,5-cyclooctadiene)(methoxy)iridium(I) dimer; 4,4'-di-tert-butyl-2,2'-bipyridine / tert-butyl methyl ether / 4 h / 80 °C / Inert atmosphere

5: copper(ll) bromide / methanol; water / 1 h / 80 °C / Inert atmosphere

6: bis-triphenylphosphine-palladium(II) chloride; 1,4-di(diphenylphosphino)-butane; tetrabutyl ammonium fluoride / dimethyl sulfoxide; tetrahydrofuran / 1 h / 110 °C / Inert atmosphere

With selenium(IV) oxide; bis-triphenylphosphine-palladium(II) chloride; (1,5-cyclooctadiene)(methoxy)iridium(I) dimer; eatons reagent; tetrabutyl ammonium fluoride; dihydrogen peroxide; potassium carbonate; 1,4-di(diphenylphosphino)-butane; 4,4'-di-tert-butyl-2,2'-bipyridine; copper(ll) bromide; In tetrahydrofuran; methanol; tert-butyl methyl ether; water; dimethyl sulfoxide; acetone; toluene; tert-butyl alcohol;