trans-[RuCl₂(S-dimethylsulfoxid)(4'-(4-methylphenyl)-2,2':6',2''-terpyridin)]

Base Information

• Chemical Name: trans-[RuCl₂(S-dimethylsulfoxid)(4'-(4-methylphenyl)-2,2':6',2''-terpyridin)]
• CAS No.: 609810-65-3
• Molecular Formula: C₂₄H₂₃Cl₂N₃ORuS
• Molecular Weight: 573.508
• Mol file: 609810-65-3.mol

Synonyms:

Chemical Property of trans-[RuCl₂(S-dimethylsulfoxid)(4'-(4-methylphenyl)-2,2':6',2''-terpyridin)]

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of trans-[RuCl₂(S-dimethylsulfoxid)(4'-(4-methylphenyl)-2,2':6',2''-terpyridin)]

There total 1 articles about trans-[RuCl₂(S-dimethylsulfoxid)(4'-(4-methylphenyl)-2,2':6',2''-terpyridin)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

dichlorotetrakis(dimethylsulfoxide)ruthenium(II) + 4'-(4-methylphenyl)-2,2':6',2-terpyridine (89972-77-0) → trans-[RuCl2(S-dimethylsulfoxid)(4'-(4-methylphenyl)-2,2':6',2''-terpyridin)] (609810-65-3)

Guidance literature:

In methanol; ethanol; Ru-compound dissolved in EtOH/MeOH (5:1); heated under reflux for 15 min; terpyridine in EtOH added; heated under reflux for 24 h; put into refrigerator; filtered; washed with water and EtOH; dried under vacuum with oil pump; elem. anal.;

DOI:10.1002/zaac.200400330

Reference yield:

1-[6-(2,2'-bipyridyl)]-1-(2-pyridyl)-ethanol (852244-36-1) + ruthenium(II)(4'-tolyl-2,2':6',2''-terpyridine)((CH3)2SO)Cl2 (609810-65-3) → ruthenium(II)(4'-tolyl-2,2':6',2''-terpyridine)(1-[6-(2,2-bipyridyl)]-1-(2-pyridyl)-ethanol) (852244-44-1)

Guidance literature:

In ethanol; water; complex prepd by react. of Ru(II)(ttpy)(DMSO)Cl2 and 1-(6-(2,2'-bipyridyl)-1-(2-pyridyl)-ethanol in refluxing ethanol/water mixt.; UV/Vis spectroscopy, NMR;

DOI:10.1039/b500946d

upstream raw materials:

4'-(4-methylphenyl)-2,2':6',2-terpyridine

Downstream raw materials:

ruthenium(II)(4'-tolyl-2,2':6',2''-terpyridine)(1-[6-(2,2-bipyridyl)]-1-(2-pyridyl)-ethanol)