SnI(Ph)(C(SiMe₃)2CH₂CH₂C(SiMe₃)2)

Base Information

• Chemical Name: SnI(Ph)(C(SiMe₃)2CH₂CH₂C(SiMe₃)2)
• CAS No.: 1014736-53-8
• Molecular Formula: C₂₂H₄₅ISi₄Sn
• Molecular Weight: 667.556
• Mol file: 1014736-53-8.mol

Synonyms:

Chemical Property of SnI(Ph)(C(SiMe₃)2CH₂CH₂C(SiMe₃)2)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of SnI(Ph)(C(SiMe₃)2CH₂CH₂C(SiMe₃)2)

There total 9 articles about SnI(Ph)(C(SiMe₃)2CH₂CH₂C(SiMe₃)2) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 45.0%

1-(trimethylsilyl)-1-hexyne (3844-94-8) + iodobenzene (591-50-4) + 2,2,5,5-tetrakis(trimethylsilyl)-1-stannacyclopentane-1,1-diyl (136213-12-2) → SnI(Ph)(C(SiMe3)2CH2CH2C(SiMe3)2) (1014736-53-8) + (((CH3)3Si)2CCH2CH2C(Si(CH3)3)2)SnI(CH(C3H7)CCSi(CH3)3) (1035852-70-0)

Guidance literature:

In further solvent(s); soln. of Sn compd. in 1-trimethylsilylhexyne added to soln. of PhI in 1-trimethylsilylhexyne by using syringe pump; stirred; volatiles removed in vac.; detd. by elem. anal., (1)H, (13)C and (119)SnNMR, IR and mass spectra;

DOI:10.1021/om800132h

Reference yield:

iodobenzene (591-50-4) + 2,2,5,5-tetrakis(trimethylsilyl)-1-stannacyclopentane-1,1-diyl (136213-12-2) → SnI(Ph)(C(SiMe3)2CH2CH2C(SiMe3)2) (1014736-53-8)

Guidance literature:

In neat (no solvent); Sn compd. mixed with PhI;

DOI:10.1021/om800132h

Reference yield:

iodobenzene (591-50-4) + 2,2,5,5-tetrakis(trimethylsilyl)-1-stannacyclopentane-1,1-diyl (136213-12-2) + cyclohexene (110-83-8) → SnI(Ph)(C(SiMe3)2CH2CH2C(SiMe3)2) (1014736-53-8) + ((CH3)3Si)4C4H4Sn(C6H9)I (1014736-65-2)

Guidance literature:

In not given; mixt. of Sn compd. and C6H5I added to C6H10;

DOI:10.1021/om8000108

upstream raw materials:

iodobenzene

2,2,5,5-tetrakis(trimethylsilyl)-1-stannacyclopentane-1,1-diyl

cyclopentene

cyclohexene

Refernces

• 1、 Kavara, Ajdin,Cousineau, Kandarpa D.,Rohr, Ahleah D.,Kampf, Jeff W.,Holl, Mark M. Banaszak. "A stannylene/aryl iodide reagent for allylic CH activation and double bond addition chemistry". . p. 1041 - 1043. Retrieved 2009/01/31.