2-mercaptobenzhydrylidenamine

Base Information

• Chemical Name: 2-mercaptobenzhydrylidenamine
• CAS No.: 174532-69-5
• Molecular Formula: C₁₃H₁₁NS
• Molecular Weight: 213.303
• Mol file: 174532-69-5.mol

Synonyms:

Chemical Property of 2-mercaptobenzhydrylidenamine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-mercaptobenzhydrylidenamine

There total 1 articles about 2-mercaptobenzhydrylidenamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

thiophenol (108-98-5) + benzonitrile (100-47-0) → 2-mercaptobenzhydrylidenamine (174532-69-5)

Guidance literature:

With n-butyllithium; N,N,N,N,-tetramethylethylenediamine; ammonium chloride; Yield given. Multistep reaction; 1.) cyclohexane, RT, 21 h, 2.) a) water, RT, 30 min, b) water, reflux, 60 min;

DOI:10.1002/jhet.5570320603

Reference yield: 80.0%

2-mercaptobenzhydrylidenamine (174532-69-5) → cis-6,12-diphenyl-6H,12H-dibenzo<1,5>dithiocin-6,12-imine

Guidance literature:

at 120 ℃; for 2h;

DOI:10.1002/jhet.5570320603

Reference yield:

2-mercaptobenzhydrylidenamine (174532-69-5) → 2-(alpha-aminobenzyl)benzenethiol

Guidance literature:

Multi-step reaction with 2 steps

1: air / 456 h / Ambient temperature

2: B₂H₆ / tetrahydrofuran / 22 h / Heating

With air; diborane; In tetrahydrofuran;

DOI:10.1002/jhet.5570320603

upstream raw materials:

thiophenol

benzonitrile

Downstream raw materials:

3-phenyl-1,2-benzoisothiazole