hydridocarbonylbis(triphenylphosphine)rhodium(I)

Base Information

• Chemical Name: hydridocarbonylbis(triphenylphosphine)rhodium(I)
• CAS No.: 22172-51-6
• Molecular Formula: C₃₇H₃₁OP₂Rh
• Molecular Weight: 656.506

Synonyms:

Chemical Property of hydridocarbonylbis(triphenylphosphine)rhodium(I)

Chemical Property:

Purity/Quality:

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Technology Process of hydridocarbonylbis(triphenylphosphine)rhodium(I)

There total 1 articles about hydridocarbonylbis(triphenylphosphine)rhodium(I) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

hydridocarbonyltris(triphenylphosphine)rhodium(I) → [RhH(CO)(P(C6H5)3)2] (22172-51-6)

Guidance literature:

In toluene; byproducts: triphenylphosphine; Rh complex hold 273 K in toluene; not isolated; detected by NMR; Kinetics;

DOI:10.1039/c39820000721

Reference yield: 97.0%

hydridocarbonylbis(triphenylphosphine)rhodium(I) (70681-19-5,22172-51-6) + tris(2-pyridyl)phosphine (26437-48-9) → carbonylhydridotriphenylphosphinebis[tris(2-pyridyl)phosphine]rhodium(I)

Guidance literature:

In Petroleum ether; benzene; stirring in benzene and petroleum for 2 h at ambient temp. under N2; the ppt. washed with toluene and petroleum, dried in vac.; elem. anal.;

DOI:10.1039/DT9800000055

Reference yield: 56.0%

hydridocarbonylbis(triphenylphosphine)rhodium(I) (70681-19-5,22172-51-6) + bis[η5-(dicyclohexylphosphino)cyclopentadienyl]dimethylzirconium (827037-58-1) + carbon monoxide (201230-82-2) → bis(carbonyl)[bis(η5-(dicyclohexylphosphino)cyclopentadienyl)methylzirconium-κ-P,P']rhodium (Rh-Zr)

Guidance literature:

In toluene; byproducts: CH4, PPh3; Ar atm.; precooled toluene was added to a stirred mixt. of complexes at room temp., stirred for 5 min at room temp., CO was bubbled through it for 10 min; the solid was filtered, washed with toluene and pentane, dried in vac.; elem. anal.;

DOI:10.1021/om049346z

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