(C₆H₅)3PAu(C₆H₄)(CH₂)2(C₆H₄)AuP(C₆H₅)3

Base Information

• Chemical Name: (C₆H₅)3PAu(C₆H₄)(CH₂)2(C₆H₄)AuP(C₆H₅)3
• CAS No.: 192137-72-7
• Molecular Formula: C₅₀H₄₂Au₂P₂
• Molecular Weight: 1098.76
• Mol file: 192137-72-7.mol

Synonyms:

Chemical Property of (C₆H₅)3PAu(C₆H₄)(CH₂)2(C₆H₄)AuP(C₆H₅)3

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of (C₆H₅)3PAu(C₆H₄)(CH₂)2(C₆H₄)AuP(C₆H₅)3

There total 1 articles about (C₆H₅)3PAu(C₆H₄)(CH₂)2(C₆H₄)AuP(C₆H₅)3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 51.0%

(triphenylphosphine)gold(I) chloride (14243-64-2) + 1,2-bis(2-bromophenyl)ethane (59485-34-6) → (C6H5)3PAu(C6H4)(CH2)2(C6H4)AuP(C6H5)3 (192137-72-7)

Guidance literature:

With n-BuLi; In tetrahydrofuran; diethyl ether; hexane; Ar-atmosphere; dropwise addn. of BuLi (in hexane) to ligand (in ether) at 0°C, stirring (room temp., 4 h), dropwise addn. to of Au-complex suspn. (in THF), stirring for 2 h; water addn., drying of org. layer (K2CO3), concn. (pptn.), filtration, treatment with ether, drying, dissoln. in THF, pptn. on addn. of ether/petroleum ether=1:1; second crop from mother liquor; elem. anal.;

DOI:10.1016/S0022-328X(96)06539-4

Reference yield: 70.0%

(triphenylphosphine)gold(I) chloride (14243-64-2) + (C6H5)3PAu(C6H4)(CH2)2(C6H4)AuP(C6H5)3 (192137-72-7) + silver tetrafluoroborate tris(tetrahydrofuranate) → (AuP(C6H5)3)4(C6H4CH2CH2C6H4)(2+)*2BF4(1-)=[(AuP(C6H5)3)4(C6H4CH2CH2C6H4)](BF4)2

Guidance literature:

In tetrahydrofuran; mixing equimolar amts. of ClAuPPh3 and AgBF4 at -60°C, addn. to 0.5 equiv. of Au-complex soln., stirring (-15°C, 1 h); pptn. on addn. of ether at -15°C, filtration, dissoln. in THF, pptn. on ether addn., filtration, drying; second crop from mother liquor; elem. anal.;

DOI:10.1016/S0022-328X(96)06539-4

upstream raw materials:

(triphenylphosphine)gold(I) chloride

1,2-bis(2-bromophenyl)ethane