dihydridotris(triphenylphosphine)ruthenium

Base Information

• Chemical Name: dihydridotris(triphenylphosphine)ruthenium
• CAS No.: 30352-62-6
• Molecular Formula: C₅₄H₄₇P₃Ru
• Molecular Weight: 889.958
• Mol file: 30352-62-6.mol

Synonyms:

Chemical Property of dihydridotris(triphenylphosphine)ruthenium

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of dihydridotris(triphenylphosphine)ruthenium

There total 4 articles about dihydridotris(triphenylphosphine)ruthenium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

dichloro(1,5-cyclooctadiene)ruthenium(II) (50982-12-2,50982-13-3) + triphenylphosphine (603-35-0) + iso-butanol (78-92-2,15892-23-6) → dihydridotris(triphenylphosphine)ruthenium (913564-49-5,30352-62-6)

Guidance literature:

With sodium hydroxide; In further solvent(s); byproducts: NaCl, C8H16; Ar or N2-atmosphere; sec.-butanol as solvent; 2 equivs. of phosphine, 20equivs. of NaOH, heating at 80°C for 3 h; cooling, addn. of H2O, collection (filtration), washing (MeOH), drying (vac.);

DOI:10.1021/om9706673

Reference yield:

dihydridotetrakis(triphenylphosphine)ruthenium (27599-25-3,54083-06-6,19529-00-1) → dihydridotris(triphenylphosphine)ruthenium (913564-49-5,30352-62-6)

Guidance literature:

With 2,2',6,6'-tetramethylpiperidine N-oxyl; In chlorobenzene; stirred at 25°C for 6 h under N2; not isolated, detected by IR;

DOI:10.1021/ja0103804

Reference yield:

{RuHCl(P(C6H5)3)3}*CH3C6H5 (1352709-70-6,217661-36-4) → dihydridotris(triphenylphosphine)ruthenium (913564-49-5,30352-62-6)

Guidance literature:

With potassium hydride; In ⁽²⁾H₈-toluene; addn. of degassed toluene-d8 to a mixt. of (RuHCl(PPh3)3)*CH3C6H5 and KH in an evacuated vessel; stirring for 4 days;; not isolated;;

DOI:10.1021/ja00244a019

upstream raw materials:

dihydridotetrakis(triphenylphosphine)ruthenium

nitrogen

dichloro(1,5-cyclooctadiene)ruthenium(II)

triphenylphosphine