3-Hexanone 2,4-dinitrophenyl hydrazone

Base Information

• Chemical Name: 3-Hexanone 2,4-dinitrophenyl hydrazone
• CAS No.: 1655-39-6
• Molecular Formula: C₁₂H₁₆N₄O₄
• Molecular Weight: 280.283
• NSC Number: 126531
• Nikkaji Number: J2.540.433E
• Mol file: 1655-39-6.mol

Synonyms:NSC126531;1655-39-6;NSC-126531;3-Hexanone 2,4-dinitrophenyl hydrazone

Chemical Property of 3-Hexanone 2,4-dinitrophenyl hydrazone

Chemical Property:

• Vapor Pressure: 8.37E-07mmHg at 25°C
• Boiling Point: 406.1°C at 760 mmHg
• Flash Point: 199.4°C
• Density: 1.29g/cm³
• XLogP3: 4.3
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 5
• Exact Mass: 280.11715500
• Heavy Atom Count: 20
• Complexity: 375

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCC(=NNC1=C(C=C(C=C1)[N+](=O)[O-])[N+](=O)[O-])CC
• Isomeric SMILES: CCC/C(=N\NC1=C(C=C(C=C1)[N+](=O)[O-])[N+](=O)[O-])/CC

Technology Process of 3-Hexanone 2,4-dinitrophenyl hydrazone

There total 4 articles about 3-Hexanone 2,4-dinitrophenyl hydrazone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

5-hydroxyhexan-3-one (33683-44-2) → hexan-3-one-(2,4-dinitro-phenylhydrazone) (1655-39-6)

Guidance literature:

Multi-step reaction with 3 steps

1: oxalic acid

2: Raney nickel / 30 - 40 °C / 73550.8 Torr / Hydrogenation

With oxalic acid; nickel;

DOI:10.1592/phco.20.19.1432.34861

Reference yield:

4-hexen-3-one (2497-21-4,50396-87-7,50396-96-8,130981-55-4,25659-22-7) → hexan-3-one-(2,4-dinitro-phenylhydrazone) (1655-39-6)

Guidance literature:

Multi-step reaction with 2 steps

1: Raney nickel / 30 - 40 °C / 73550.8 Torr / Hydrogenation

With nickel;

DOI:10.1592/phco.20.19.1432.34861

Reference yield:

n-hexan-3-one (589-38-8) + (2,4-dinitro-phenyl)-hydrazine (119-26-6) → hexan-3-one-(2,4-dinitro-phenylhydrazone) (1655-39-6)

Guidance literature:

DOI:10.1039/jr9420000733 DOI:10.1592/phco.20.19.1432.34861

upstream raw materials:

n-hexan-3-one

(2,4-dinitro-phenyl)-hydrazine

5-hydroxyhexan-3-one

4-hexen-3-one