{2-(1,3-benzothiazol-2-yl)-6-[(diphenylthiophosphoryl)amino]phenyl}palladium chloride

Base Information

• Chemical Name: {2-(1,3-benzothiazol-2-yl)-6-[(diphenylthiophosphoryl)amino]phenyl}palladium chloride
• CAS No.: 1305316-90-8
• Molecular Formula: C₂₅H₁₈ClN₂PPdS₂
• Molecular Weight: 583.41
• Mol file: 1305316-90-8.mol

Synonyms:

Chemical Property of {2-(1,3-benzothiazol-2-yl)-6-[(diphenylthiophosphoryl)amino]phenyl}palladium chloride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of {2-(1,3-benzothiazol-2-yl)-6-[(diphenylthiophosphoryl)amino]phenyl}palladium chloride

There total 2 articles about {2-(1,3-benzothiazol-2-yl)-6-[(diphenylthiophosphoryl)amino]phenyl}palladium chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

bis(benzonitrile)palladium(II) dichloride (15617-18-2,39958-10-6,14220-64-5) + N-[3-(1,3-benzothiazol-2-yl)phenyl]-P,P-diphenylthiophosphinic acid amide (1305316-86-2) → {2-(1,3-benzothiazol-2-yl)-6-[(diphenylthiophosphoryl)amino]phenyl}palladium chloride (1305316-90-8)

Guidance literature:

In acetonitrile; soln. of Pd complex in MeCN was slowly added to suspn. of ligand in MeCN; stirred under reflux for 2 h; cooled to room temp.; filtered; washed (MeCN, Et2O); dried (vac.); elem.anal.;

DOI:10.1021/om101012r

Reference yield: 51.0%

[(Ph2P(S)NHC6H4C7H4NS)PdCl2] → {2-(1,3-benzothiazol-2-yl)-6-[(diphenylthiophosphoryl)amino]phenyl}palladium chloride (1305316-90-8)

Guidance literature:

In neat (no solvent, solid phase); byproducts: HCl; heating palladium compd. at 200°C for 15 min; dissolving in DMSO/CH2Cl2 (1:3), filtration, concg., addn. of ethanol, isolation of ppt., NMR and MS;

DOI:10.1039/c1dt10680e

upstream raw materials:

bis(benzonitrile)palladium(II) dichloride

N-[3-(1,3-benzothiazol-2-yl)phenyl]-P,P-diphenylthiophosphinic acid amide