2,5-diisopropylthiophenol

Base Information

• Chemical Name: 2,5-diisopropylthiophenol
• CAS No.: 6807-50-7
• Molecular Formula: C₁₂H₁₈S
• Molecular Weight: 194.341
• Mol file: 6807-50-7.mol

Synonyms:

Chemical Property of 2,5-diisopropylthiophenol

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2,5-diisopropylthiophenol

There total 3 articles about 2,5-diisopropylthiophenol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Dimethyl-thiocarbamic acid S-(2,5-diisopropyl-phenyl) ester (1027384-72-0) → 2,5-diisopropylthiophenol (6807-50-7)

Guidance literature:

With potassium hydroxide; In tetrahydrofuran; methanol; for 3h; Ambient temperature;

DOI:10.1021/jo00279a041

Reference yield:

Dimethyl-thiocarbamic acid O-(2,5-diisopropyl-phenyl) ester → 2,5-diisopropylthiophenol (6807-50-7)

Guidance literature:

Multi-step reaction with 2 steps

1: 3 h / 290 - 310 °C

2: LAH / diethyl ether / Ambient temperature

With lithium aluminium tetrahydride; In diethyl ether;

DOI:10.1021/jm970615f

Reference yield:

2,5-Diisopropylphenol (35946-91-9) → 2,5-diisopropylthiophenol (6807-50-7)

Guidance literature:

Multi-step reaction with 3 steps

1: 1.) NaH / 1.) DMF, 1 h, 2.) DMF, 60 deg C, 18 h

2: 3 h / 290 - 310 °C

3: LAH / diethyl ether / Ambient temperature

With lithium aluminium tetrahydride; sodium hydride; In diethyl ether;

DOI:10.1021/jm970615f

upstream raw materials:

Dimethyl-thiocarbamic acid S-(2,5-diisopropyl-phenyl) ester

2,5-Diisopropylphenol

Downstream raw materials:

2,5-diisopropylphenyl disulfide

Refernces

• 1、 Krishnamurthy, S.,Aimino, D.. "Rapid and Selective Reduction of Functionalized Aromatic Disulfides with Lithium Tri-tert-butoxyaluminohydride. A Remarkable Steric and Electronic Control. Comparison of Various Hydride Reagents". . p. 4458 - 4462. Retrieved 2007/10/02.