Divinylphenylphosphine oxide

Base Information

• Chemical Name: Divinylphenylphosphine oxide
• CAS No.: 13815-96-8
• Molecular Formula: C10H11OP
• Molecular Weight: 178.171
• DSSTox Substance ID: DTXSID301306618
• Nikkaji Number: J408.224I
• Mol file: 13815-96-8.mol

Synonyms:divinylphenylphosphine oxide;13815-96-8;Phenyldivinylphosphine oxide;Diethenylphenylphosphine oxide;divinyl-phenyl-phosphine oxide;phenyl(divinyl)phosphine oxide;SCHEMBL894129;QJPDCMIFPPRCFH-UHFFFAOYSA-N;DTXSID301306618

Chemical Property of Divinylphenylphosphine oxide

Chemical Property:

• XLogP3: 1.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 3
• Exact Mass: 178.054751968
• Heavy Atom Count: 12
• Complexity: 202

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C=CP(=O)(C=C)C1=CC=CC=C1

Technology Process of Divinylphenylphosphine oxide

There total 7 articles about Divinylphenylphosphine oxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

P,P-dichlorophenylphosphine oxide (824-72-6) + vinyl magnesium bromide (1826-67-1) → divinyl phenyl phosphine oxide (13815-96-8)

Guidance literature:

In tetrahydrofuran; diethyl ether; at -70 ℃; for 3h;

DOI:10.1016/j.tet.2005.01.019

Reference yield: 69.0%

[dodec-1-enyl(vinyl)phosphoryl]-benzene (849669-08-5) + styrene (100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6) → [bis-(2-phenyl-vinyl)-phosphoryl]-benzene + [(2-phenyl-vinyl)(dodec-1-enyl)phosphoryl]-benzene + (di-dodec-1-enyl-phosphoryl)-benzene + divinyl phenyl phosphine oxide (13815-96-8)

Guidance literature:

chiral Ru-based catalyst; In dichloromethane; for 48h; Heating;

DOI:10.1016/j.tet.2005.01.019

Reference yield:

Bis(2-bromethyl)-phenylphosphinoxid (37912-68-8) → divinyl phenyl phosphine oxide (13815-96-8)

Guidance literature:

With triethylamine; In benzene;

upstream raw materials:

Bis(2-bromethyl)-phenylphosphinoxid

divinylphenylphosphine

[dodec-1-enyl(vinyl)phosphoryl]-benzene

styrene

Downstream raw materials:

1-methyl-4-phenyl-4-oxotetrahydro-1,4-azaphosphorinane

(2R,3aR)-6,6-Dimethyl-2-(phenyl-vinyl-phosphinoyl)-hexahydro-pyrrolo[1,2-b]isoxazole

(2S,3aS)-6,6-Dimethyl-2-(phenyl-vinyl-phosphinoyl)-hexahydro-pyrrolo[1,2-b]isoxazole

7,7-Dimethyl-4-phenyl-8-oxa-1-aza-4-phospha-bicyclo[3.2.1]octane 4-oxide