{bis(diphenylphosphino)methane}bis(trifluoroacetato)palladium(II)

Base Information

Chemical Name:{bis(diphenylphosphino)methane}bis(trifluoroacetato)palladium(II)
CAS No.:94791-45-4
Molecular Formula:C₂₉H₂₂F₆O₄P₂Pd
Molecular Weight:716.849
Hs Code.:

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Chemical Property of {bis(diphenylphosphino)methane}bis(trifluoroacetato)palladium(II)

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Technology Process of {bis(diphenylphosphino)methane}bis(trifluoroacetato)palladium(II)

There total 2 articles about {bis(diphenylphosphino)methane}bis(trifluoroacetato)palladium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

: 3375-31-3
palladium diacetate

: 76-05-1
trifluoroacetic acid

: 2071-20-7
bis-diphenylphosphinomethane

: 94791-45-4
{bis(diphenylphosphino)methane}bis(trifluoroacetato)palladium(II)

Guidance literature:: In acetone; trifluoroacetic acid; under N2, Pd(OAc)2 dissolved in acetone-CF3COOH (9:1 v/v) and soln. of Ph2PCH2PPh2 in acetone added (3 h); evapd. under vac., recrystd. from acetone-pentane; elem. anal.;
DOI:10.1039/DT9870000201

Reference yield: 52.0%

: 3375-31-3
palladium diacetate

: 76-05-1
trifluoroacetic acid

: 2071-20-7
bis-diphenylphosphinomethane

: 94791-45-4
{bis(diphenylphosphino)methane}bis(trifluoroacetato)palladium(II)

: 94791-47-6
(palladium(I))2(bis(diphenylphosphino)methane)2-bis(trifluoroacetate)

Guidance literature:: With CO; In acetone; Pd(OAc)2 and org. ligand dissoln. under N2, CF3COOH addn. and CO bubbling (14 h, room temp.); soln. filtering and evapn. to dryness, residue left under vac. for 1 h; resulting oil dissoln. (acetone); pptn. of Pd2-complex (toluene and hexane), recrystn. (CH2Cl2/hexane); crystn. from filtrate yields Pd1-complex; elem. anal.;

Reference yield:

: 94791-45-4
{bis(diphenylphosphino)methane}bis(trifluoroacetato)palladium(II)

: (palladium(I))2(bis(diphenylphosphino)methane)2(μ-CO)(OCOCF3)2

Guidance literature:: Multi-step reaction with 2 steps

1: water; acetone; trifluoroacetic acid

2: benzene

In water; acetone; trifluoroacetic acid; benzene;