bis(triphenylphosphoranyliden)ammonium gold(III) bis(dithiolene)

Base Information

• Chemical Name: bis(triphenylphosphoranyliden)ammonium gold(III) bis(dithiolene)
• CAS No.: 492470-33-4
• Molecular Formula: C₂₄H₁₂AuS₁₀*C₃₆H₃₀NP₂
• Molecular Weight: 1356.57
• Mol file: 492470-33-4.mol

Synonyms:

Chemical Property of bis(triphenylphosphoranyliden)ammonium gold(III) bis(dithiolene)

Chemical Property:

Purity/Quality:

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MSDS Files:

Useful:

Technology Process of bis(triphenylphosphoranyliden)ammonium gold(III) bis(dithiolene)

There total 2 articles about bis(triphenylphosphoranyliden)ammonium gold(III) bis(dithiolene) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 38.0%

2Na(1+)*(SC2(C4SH3))2S(2-)=Na2(SC2(C4H3S))2S + bis(triphenylphosphoranyliden)ammonium tetrachlorogold(III) (121772-60-9) → bis(triphenylphosphoranyliden)ammonium gold(III) bis(dithiolene) (492470-33-4)

Guidance literature:

In tetrahydrofuran; soln. of dithiolate added to gold complex;

DOI:10.1039/b206243g

Reference yield: 38.0%

bis(triphenylphosphoranyliden)ammonium tetrachlorogold(III) (121772-60-9) + 4,6-di-thiophen-2-yl-thieno[3,4-d][1,3]dithiol-2-one (288145-57-3) → bis(triphenylphosphoranyliden)ammonium gold(III) bis(dithiolene) (492470-33-4)

Guidance literature:

With CH₃CH₂ONa; In tetrahydrofuran; (N2); addn. of EtONa to a soln. of ligand in THF, reflux for 15 min, addn. of metal complex, stirring overnight; evapn. in vac., crystn. (THF/Et2O); elem. anal.;

DOI:10.1039/b801187g

upstream raw materials:

bis(triphenylphosphoranyliden)ammonium tetrachlorogold(III)

4,6-di-thiophen-2-yl-thieno[3,4-d][1,3]dithiol-2-one