bis(triphenylphosphoranyliden)ammonium tetrachlorogold(III)

Base Information

• Chemical Name: bis(triphenylphosphoranyliden)ammonium tetrachlorogold(III)
• CAS No.: 121772-60-9
• Molecular Formula: AuCl₄*C₃₆H₃₀NP₂
• Molecular Weight: 877.367

Synonyms:bis(triphenylphosphoranyliden)ammonium tetrachlorogold(III)

Chemical Property of bis(triphenylphosphoranyliden)ammonium tetrachlorogold(III)

Chemical Property:

Purity/Quality:

98% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
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Technology Process of bis(triphenylphosphoranyliden)ammonium tetrachlorogold(III)

There total 4 articles about bis(triphenylphosphoranyliden)ammonium tetrachlorogold(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

bis(triphenylphosphine)nitrogen gold dichloride (106402-58-8) + (Dichloroiodo)benzene (932-72-9) → bis(triphenylphosphoranyliden)ammonium tetrachlorogold(III) (121772-60-9)

Guidance literature:

In not given;

DOI:10.1021/ja036049x

Reference yield:

sodium tetrachloroaurate (III) hydrate (948055-59-2,29156-65-8) + bis(triphenylphosphine)iminium chloride (21050-13-5) → bis(triphenylphosphoranyliden)ammonium tetrachlorogold(III) (121772-60-9)

Guidance literature:

In not given; equimolar amts.;

Reference yield:

Na(1+)*[AuCl4](1-)*99H2O=Na[AuCl4]*99H2O + bis(triphenylphosphine)iminium chloride (21050-13-5) → bis(triphenylphosphoranyliden)ammonium tetrachlorogold(III) (121772-60-9)

Guidance literature:

In acetone; (N2); Schlenk technique; Au complex and salt were reacted in acetone;

DOI:10.1021/ic049132+

upstream raw materials:

bis(triphenylphosphoranylidene)ammonium dichloroaurate(I)

chlorine

sodium tetrachloroaurate (III) hydrate

bis(triphenylphosphine)iminium chloride

Downstream raw materials:

(triphenylphosphine)gold(I) chloride

cis-bis(triphenylphosphine)iminium[Au(mesityl)2Cl₂]

bis(triphenylphosphoranyliden)ammonium gold(III) bis(dithiolene)

N(P(C₆H₅)3)2⁽¹⁺⁾*Au(S₂C₂B₁₀H₁₀)2^(1-) = [N(P(C₆H₅)3)2][Au(S₂C₂B₁₀H₁₀)2]

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