5-(6-[5-(1-imidazolyl)pentanoyloxy]-2-(3-methoxy-2,2-dimethylpropanoyloxy)phenyl)-10,15,20-tris[2,6-bis(3-methoxy-2,2-dimethylpropanoyloxy)phenyl]porphinatoiron(II)

Base Information

• Chemical Name: 5-(6-[5-(1-imidazolyl)pentanoyloxy]-2-(3-methoxy-2,2-dimethylpropanoyloxy)phenyl)-10,15,20-tris[2,6-bis(3-methoxy-2,2-dimethylpropanoyloxy)phenyl]porphinatoiron(II)
• CAS No.: 432548-00-0
• Molecular Formula: C₉₄H₁₀₈FeN₆O₂₃
• Molecular Weight: 1745.76

Synonyms:

Chemical Property of 5-(6-[5-(1-imidazolyl)pentanoyloxy]-2-(3-methoxy-2,2-dimethylpropanoyloxy)phenyl)-10,15,20-tris[2,6-bis(3-methoxy-2,2-dimethylpropanoyloxy)phenyl]porphinatoiron(II)

Chemical Property:

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Useful:

Technology Process of 5-(6-[5-(1-imidazolyl)pentanoyloxy]-2-(3-methoxy-2,2-dimethylpropanoyloxy)phenyl)-10,15,20-tris[2,6-bis(3-methoxy-2,2-dimethylpropanoyloxy)phenyl]porphinatoiron(II)

There total 2 articles about 5-(6-[5-(1-imidazolyl)pentanoyloxy]-2-(3-methoxy-2,2-dimethylpropanoyloxy)phenyl)-10,15,20-tris[2,6-bis(3-methoxy-2,2-dimethylpropanoyloxy)phenyl]porphinatoiron(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

chloro(5-(6-[5-(1-imidazolyl)pentanoyloxy]-2-(3-methoxy-2,2-dimethylpropanoyloxy)phenyl)-10,15,20-tris[2,6-bis(3-methoxy-2,2-dimethylpropanoyloxy)phenyl]porphinato)iron(III) → 5-(6-[5-(1-imidazolyl)pentanoyloxy]-2-(3-methoxy-2,2-dimethylpropanoyloxy)phenyl)-10,15,20-tris[2,6-bis(3-methoxy-2,2-dimethylpropanoyloxy)phenyl]porphinatoiron(II) (432548-00-0)

Guidance literature:

With sodium dithionite; In water; toluene; redn. using aq. Na2S2O4 in heterogeneous two-phase system under N2; sepn. of two phases, detected in org. layer by UV spectroscopy;

DOI:10.1246/bcsj.74.1695

Reference yield:

((C3H3N2(CH2)4CO2)(CH3OCH2C(CH3)2CO2)C6H3)((CH3OCH2C(CH3)2CO2)2C6H3)3C20H8N4Fe(O2) → 5-(6-[5-(1-imidazolyl)pentanoyloxy]-2-(3-methoxy-2,2-dimethylpropanoyloxy)phenyl)-10,15,20-tris[2,6-bis(3-methoxy-2,2-dimethylpropanoyloxy)phenyl]porphinatoiron(II) (432548-00-0)

Guidance literature:

In water; toluene; byproducts: O2; in H2O-satd. toluene at 25°C; rate constant measured by a competitive rebinding technique using laser-flash photolysis app.; not isolated, detected by UV spectroscopy; Kinetics;

DOI:10.1246/bcsj.74.1695

Reference yield:

5-(6-[5-(1-imidazolyl)pentanoyloxy]-2-(3-methoxy-2,2-dimethylpropanoyloxy)phenyl)-10,15,20-tris[2,6-bis(3-methoxy-2,2-dimethylpropanoyloxy)phenyl]porphinatoiron(II) (432548-00-0) + carbon monoxide (201230-82-2) → carbonyl(5-(6-[5-(1-imidazolyl)pentanoyloxy]-2-(3-methoxy-2,2-dimethylpropanoyloxy)phenyl)-10,15,20-tris[2,6-bis(3-methoxy-2,2-dimethylpropanoyloxy)phenyl]porphinato)iron(II)

Guidance literature:

In water; toluene; 20 μM Fe(II) complex in H2O-satd. toluene; measurement of rate constant by a competitive rebinding technique using laser-flash photolysis app.; at 25°C; not isolated; Kinetics;

DOI:10.1246/bcsj.74.1695

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