trans-[Pd(μ-Cl)(COPh)(C(NEt2)Ph)]2

Base Information

Chemical Name:trans-[Pd(μ-Cl)(COPh)(C(NEt2)Ph)]2
CAS No.:1049746-76-0
Molecular Formula:C₃₆H₄₀Cl₂N₂O₂Pd₂
Molecular Weight:816.472
Hs Code.:

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Chemical Property of trans-[Pd(μ-Cl)(COPh)(C(NEt2)Ph)]2

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Technology Process of trans-[Pd(μ-Cl)(COPh)(C(NEt2)Ph)]2

There total 2 articles about trans-[Pd(μ-Cl)(COPh)(C(NEt2)Ph)]2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 59.0%

: (CO)5WC(C₆H₅)(N(C₂H₅)2)

: 1049638-29-0
[Pd(μ-Cl)Ph(SMe2)]2

: 1049746-76-0,1049638-31-4
trans-[Pd(μ-Cl)(COPh)(C(NEt2)Ph)]2

Guidance literature:: In acetonitrile; under N2; Pd complex added to soln. of W complex in MeCN at room temp.; stirred for 5 h; filtered through activated carbon and Celite; filtrate evapd. to dryness; EtOH added; kept at -20°C for 30 min; filtered; ppt. washed with Et2O; air dried; recrystd. (CH2Cl2-Et2O, -20°C); filtered (activated carbon and Celite); elem. anal.;
DOI:10.1021/om800358f

Reference yield:

: 1049746-76-0,1049638-31-4
trans-[Pd(μ-Cl)(COPh)(C(NEt2)Ph)]2

: 1049746-76-0,1049638-31-4
cis-[Pd(μ-Cl)(COPh)(C(NEt2)Ph)]2

Guidance literature:: In chloroform-d1; under N2; Pd complex dissolved in CDCl3 at 293 K; mixt. of trans and cisisomers (10:1) obtained; not isolated; detd. by (1)H and (13)C NMR spectra;
DOI:10.1021/om800358f

Reference yield: 81.0%

: 1049746-76-0,1049638-31-4
trans-[Pd(μ-Cl)(COPh)(C(NEt2)Ph)]2

: 603-35-0
triphenylphosphine

: 1049638-33-6
PdCl(C(O)C₆H₅)(C(C₆H₅)N(C₂H₅)2)(P(C₆H₅)3)

Guidance literature:: In dichloromethane; under N2; PPh3 added to soln. of Pd complex in CH2Cl2 at room temp.; stirred for 1.5 h; evapd. to dryness; n-hexane added; stirred for 1 h at -20°C; filtered; ppt. washed with cold n-hexane; air dried; recrystd. from CH2Cl2-Et2O at -20°C; filtered through activated carbon and Celite; elem.anal.;
DOI:10.1021/om800358f