zinc(II) 2,9,16-tri-tert-butyl-23-(4'-bromomethylphenyl)phthalocyaninato^(2-)-N₂₉,N₃₀,N₃₁,N₃₂

Base Information

• Chemical Name: zinc(II) 2,9,16-tri-tert-butyl-23-(4'-bromomethylphenyl)phthalocyaninato^(2-)-N₂₉,N₃₀,N₃₁,N₃₂
• CAS No.: 1301766-46-0
• Molecular Formula: C₅₁H₄₅BrN₈Zn
• Molecular Weight: 915.266
• Mol file: 1301766-46-0.mol

Synonyms:

Chemical Property of zinc(II) 2,9,16-tri-tert-butyl-23-(4'-bromomethylphenyl)phthalocyaninato^(2-)-N₂₉,N₃₀,N₃₁,N₃₂

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of zinc(II) 2,9,16-tri-tert-butyl-23-(4'-bromomethylphenyl)phthalocyaninato^(2-)-N₂₉,N₃₀,N₃₁,N₃₂

There total 1 articles about zinc(II) 2,9,16-tri-tert-butyl-23-(4'-bromomethylphenyl)phthalocyaninato^(2-)-N₂₉,N₃₀,N₃₁,N₃₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

carbon tetrabromide (558-13-4) + zinc(II) 2,9,16-tri-tert-butyl-23-(4'-hydroxymethylphenyl)phthalocyaninato(2-)-N29,N30,N31,N32 (1301766-45-9) → zinc(II) 2,9,16-tri-tert-butyl-23-(4'-bromomethylphenyl)phthalocyaninato(2-)-N29,N30,N31,N32 (1301766-46-0)

Guidance literature:

With P(C₆H₅)3; In dichloromethane; P(C6H5)3 and CBr4 were added to a soln. of Zn-complex in dry CH2Cl2 under Ar atm., stirred at 50°C for 1 h; washed with a satd. aq. NaHCO3, dried over MgSO4, vac. concd., column chromy. on silica gel with hexane/dioxane (3:1) as eluent;

DOI:10.1039/c0dt01348j

upstream raw materials:

carbon tetrabromide

zinc(II) 2,9,16-tri-tert-butyl-23-(4'-hydroxymethylphenyl)phthalocyaninato^(2-)-N₂₉,N₃₀,N₃₁,N₃₂