Pt(CO)(PPh₃)3

Base Information

• Chemical Name: Pt(CO)(PPh₃)3
• CAS No.: 15376-99-5
• Molecular Formula: C₅₅H₄₅OP₃Pt
• Molecular Weight: 1009.96
• Mol file: 15376-99-5.mol

Synonyms:

Chemical Property of Pt(CO)(PPh₃)3

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Pt(CO)(PPh₃)3

There total 6 articles about Pt(CO)(PPh₃)3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

Pt2[μ-P(t-Bu)2]2(H)2[P(t-Bu)2H]2 (159984-43-7) + carbon monoxide (201230-82-2) + triphenylphosphine (603-35-0) → Pt(CO)(PPh3)3 (15376-99-5)

Guidance literature:

In toluene; absence of air and moisture; stirring under CO (80°C, 4 h); concn., pptn. on hexane addn., collection (filtration), drying (vac.);

DOI:10.1021/ic9602308

Reference yield: 36.0%

Pt(C(2)H2CO)(P(C6H5)3)2 (96705-37-2) → Pt(CO)(PPh3)3 (15376-99-5)

Guidance literature:

In acetone; byproducts: C2D4, C3D6, C4D8; heating at 55°C;

Reference yield: 6.0%

tetrakis(triphenylphosphine)platinum (14221-02-4) + [Mn(C7F7)(CO)5] → Pt(CO)(PPh3)3 (15376-99-5) + [Pt(P(C6H5)3)2(C7F7)Mn(CO)4(P(C6H5)3)]

Guidance literature:

In benzene; soln. of Pt complex in C6H6 added to soln. of Mn complex under N2, mixture stirred at room temp. for 24 h; removal of solvent, chromy. (Florisil, EtOH), concn., filtration, addn.of light petroleum; elem. anal.;

DOI:10.1016/S0022-328X(00)83411-7

upstream raw materials:

tris(triphenylphosphine)platinum⁽⁰⁾

ethylenebis(triphenylphosphine)platinum⁽⁰⁾

carbon suboxide

Pt2[μ-P(t-Bu)2]2(H)2[P(t-Bu)2H]2

Downstream raw materials:

dicarbonylbis(triphenylphosphine)platinum⁽⁰⁾