iron(η2-CS2(CH(C6H5)CH2COCH3))(carbonyl)2((phenyl)3phosphine)2{BF4}

Base Information

• Chemical Name: iron(η2-CS2(CH(C6H5)CH2COCH3))(carbonyl)2((phenyl)3phosphine)2{BF4}
• CAS No.: 110904-37-5
• Molecular Formula: BF₄*C₄₉H₄₁FeO₃P₂S₂
• Molecular Weight: 946.594
• Mol file: 110904-37-5.mol

Synonyms:

Chemical Property of iron(η2-CS2(CH(C6H5)CH2COCH3))(carbonyl)2((phenyl)3phosphine)2{BF4}

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of iron(η2-CS2(CH(C6H5)CH2COCH3))(carbonyl)2((phenyl)3phosphine)2{BF4}

There total 1 articles about iron(η2-CS2(CH(C6H5)CH2COCH3))(carbonyl)2((phenyl)3phosphine)2{BF4} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

tetrafluoroboric acid diethyl ether (67969-82-8) + iron(η2-CS2)(carbonyl)2(PPh3)2 (64424-68-6) + 1-Phenylbut-1-en-3-one (122-57-6) → iron(η2-CS2(CH(C6H5)CH2COCH3))(carbonyl)2((phenyl)3phosphine)2{BF4} (110904-37-5)

Guidance literature:

In dichloromethane; Addn. of HBF4*OEt2 to Fe(η2-CS2)(CO)2(PPh3)2 in CH2Cl2 (N2), further addn. of CH2Cl2 soln. of benzylideneacetone, stirring (15 min, room temp.).; Concg., addn. of diethylether leads to pptn. of salt, elem. anal.;

DOI:10.1021/om00091a013

Reference yield: 30.0%

iron(η2-CS2(CH(C6H5)CH2COCH3))(carbonyl)2((phenyl)3phosphine)2{BF4} (110904-37-5) + magnesium (7439-95-4) → (iron)2S2C2(SCH(C6H5)CH2COCH3)2(carbonyl)4((phenyl)3phosphine)2 (110904-41-1)

Guidance literature:

In tetrahydrofuran; Addn. of Fe(η2-CS2(CH(C6H5)CH2COCH3))(CO)2(PPh3)2(BF4) in THF to activated Mg (prepd. by stirring Mg with HgCl2 in THF for 30 min, decanting, washing of Mg (THF)), stirring at room temp. for 24 h (N2).; Filtration, evapn. of solvent, silica-gel chromy. (under N2, eluant: hexane/ether). Elem. anal.;

DOI:10.1021/om00091a013

Reference yield:

iron(η2-CS2(CH(C6H5)CH2COCH3))(carbonyl)2((phenyl)3phosphine)2{BF4} (110904-37-5) → iron((CH(C6H5)CH2COCH3)2tetrathiooxalate)(carbonyl)2((phenyl)3phosphine) (110904-45-5)

Guidance literature:

Multi-step reaction with 2 steps

1: tetrahydrofuran

2: air / tetrahydrofuran

With air; In tetrahydrofuran;

DOI:10.1021/om00091a013

upstream raw materials:

tetrafluoroboric acid diethyl ether

iron(η2-CS2)(carbonyl)2(PPh3)2

1-Phenylbut-1-en-3-one

Downstream raw materials:

(iron)2S₂C₂(SCH(C₆H₅)CH₂COCH₃)2(carbonyl)4((phenyl)3phosphine)2

iron((CH(C₆H₅)CH₂COCH₃)2tetrathiooxalate)(carbonyl)2((phenyl)3phosphine)

Refernces