trans-Ni(P(C₆H₅)3)2I₂

Base Information

Chemical Name:trans-Ni(P(C₆H₅)3)2I₂
CAS No.:787624-20-8
Molecular Formula:C₃₆H₃₀I₂NiP₂
Molecular Weight:837.081
Hs Code.:

trans-Ni(P(C<sub>6</sub>H<sub>5</sub>)3)2I<sub>2</sub>

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of trans-Ni(P(C₆H₅)3)2I₂

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Technology Process of trans-Ni(P(C₆H₅)3)2I₂

There total 11 articles about trans-Ni(P(C₆H₅)3)2I₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 14.0%

: 591-50-4
iodobenzene

: 57584-08-4
hydridotris(triphenylphosphine)nickel bromide

: 787624-20-8,14057-03-5
bis(triphenylphosphine)nickel(II) diiodide

: Ni(triphenylphosphine)2(Ph)(I)

: 106625-04-1
[(C₆H₅)4P]⁽¹⁺⁾*[((C₆H₅)3P)NiI₃]^(1-)=[(C₆H₅)4P][((C₆H₅)3P)NiI₃]

Guidance literature:: In neat (no solvent); byproducts: [(C6H5)4P]I, H2; addn. of C6H5I to ((C6H5)3P)3Ni(H)Br (2.33 mmol); stirring for 24 h at 22°C (Ar-atmosphere);; pptn.; filtering out, washing with ether and drying in vac.; washing product mixt. with CH3NO2 (residue of C6H5Ni(P(C6H5)3)2I, recrystn. from C6H6); evapg. of exts. to min. vol. (isolation of ((C6H5)3P)2NiI2 from mother soln.); elem. anal., gas chromy.;;

Reference yield:

: 13462-90-3
nickel(II) iodide

: 603-35-0
triphenylphosphine

: 787624-20-8,14057-03-5
bis(triphenylphosphine)nickel(II) diiodide

Guidance literature:: In butan-1-ol; refluxing for 2 h; recrystn. from butanol;

Reference yield:

: 13462-90-3
nickel(II) iodide

: 787624-20-8,14057-03-5
bis(triphenylphosphine)nickel(II) diiodide

Guidance literature:: With triphenylphosphine; In not given; prepd. from NiI2 and PPh3 in 1-butanol or EtOH by method of R.G.Hayter and F.S.Humiec, Inorg. Chem., 4, 1701 (1965);
DOI:10.1246/bcsj.60.1589