tricarbonyl-η(3:CH)-2-methyl-E-3-(3(8),6-m-menthadiene-6-yl)-2-butene-1-yl-manganese

Base Information

Chemical Name:tricarbonyl-η(3:CH)-2-methyl-E-3-(3(8),6-m-menthadiene-6-yl)-2-butene-1-yl-manganese
CAS No.:107883-18-1
Molecular Formula:C₁₈H₂₃MnO₃
Molecular Weight:342.317
Hs Code.:

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Chemical Property of tricarbonyl-η(3:CH)-2-methyl-E-3-(3(8),6-m-menthadiene-6-yl)-2-butene-1-yl-manganese

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Technology Process of tricarbonyl-η(3:CH)-2-methyl-E-3-(3(8),6-m-menthadiene-6-yl)-2-butene-1-yl-manganese

There total 2 articles about tricarbonyl-η(3:CH)-2-methyl-E-3-(3(8),6-m-menthadiene-6-yl)-2-butene-1-yl-manganese which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 24.0%

: 10170-69-1
dimanganese decacarbonyl

: 598-25-4
Dimethylallene

: (η3-CH2CHC(CH3)2)Mn(CO)4

: 71713-52-5
C₅H₉Mn(CO)4

: 107883-18-1
tricarbonyl-η(3:CH)-2-methyl-E-3-(3(8),6-m-menthadiene-6-yl)-2-butene-1-yl-manganese

: octacarbonyl-μ-η(2:2)-1.1-dimethylallene-dimanganese(0)

: hexacarbonyl-μ-η(3:CH:3:CH)-2,3,4,5-tetramethyl-2,5-hexadiene-1,4-diyl-dimanganese

Guidance literature:: In hexane; Irradiation (UV/VIS); IR-conducted UV irradiation of a solution of 2.13 mmol of Mn2(CO)10 and20 mmol 1.1-dimethylallene in 700 ml n-hexane at 248 K under N2, filtration and evaporation;; HPLC (n-hexane, 3rd, 5th and 6th zone (octa-, tri- or hexacarbonyl compound), recrystallization from n-hexane at 183 K); 2nd zone (tetracarbonyl compounds) (yield 12 %, purification by distillation); elem. anal., NMR and IR spectroscopy;;
DOI:10.1016/0022-328X(86)80085-7

Reference yield:

: tetracarbonyl-η(3:CH)-2-methyl-E-3-(3(8),6-m-menthadiene-6-yl)-2-butene-1-yl-manganese

: 107883-18-1
tricarbonyl-η(3:CH)-2-methyl-E-3-(3(8),6-m-menthadiene-6-yl)-2-butene-1-yl-manganese

Guidance literature:: In hexane; byproducts: CO; passing N2 at 25°C through a solution of the tetracarbonyl compound in n-hexane;;
DOI:10.1016/0022-328X(86)80085-7

Reference yield: 100.0%

: 107883-18-1
tricarbonyl-η(3:CH)-2-methyl-E-3-(3(8),6-m-menthadiene-6-yl)-2-butene-1-yl-manganese

: 201230-82-2
carbon monoxide

: tetracarbonyl-η(3:CH)-2-methyl-E-3-(3(8),6-m-menthadiene-6-yl)-2-butene-1-yl-manganese

Guidance literature:: In hexane; saturating a solution of 0.06 mmol of the tricarbonyl compound in 5 ml n-hexane with CO at 194K; at room temp. the CO-addition is reversible (passing of N2 through the soln. gives the former tricarbonyl complex):; evapn. of hexane at 248K gives oily (Mn(CO)4C15H23); elem. anal., NMR and IR spectroscopy;;
DOI:10.1016/0022-328X(86)80085-7