(η5-cyclopentadienyl)(η1-(thiomethoxy)methyl)triphenylphosphinenickel(II)

Base Information

Chemical Name:(η5-cyclopentadienyl)(η1-(thiomethoxy)methyl)triphenylphosphinenickel(II)
CAS No.:96348-87-7
Molecular Formula:C₂₅H₂₅NiPS
Molecular Weight:447.203
Hs Code.:

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Chemical Property of (η5-cyclopentadienyl)(η1-(thiomethoxy)methyl)triphenylphosphinenickel(II)

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Technology Process of (η5-cyclopentadienyl)(η1-(thiomethoxy)methyl)triphenylphosphinenickel(II)

There total 2 articles about (η5-cyclopentadienyl)(η1-(thiomethoxy)methyl)triphenylphosphinenickel(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

: 23777-40-4
bis(triphenylphosphine)ethylenenickel⁽⁰⁾

: cyclopentadienyl sodium*1,2-dimethoxyethane

: 96348-87-7
(η5-cyclopentadienyl)(η1-(thiomethoxy)methyl)triphenylphosphinenickel(II)

Guidance literature:: In tetrahydrofuran; suspn. of complex in THF was treated with NaC5H5*glyme, soln. was stirred for 1 h (N2); evapd., ppt. was extd. with ether, filtered, reduced in vol., hexane was added, ppt. was washed with hexane, dried under vac.;
DOI:10.1021/om00126a007

Reference yield: 67.0%

: chloro(cyclopentadienyl)(triphenylphosphine)nickel(II)

: 10415-47-1
(methylthio)methyllithium

: 96348-87-7
(η5-cyclopentadienyl)(η1-(thiomethoxy)methyl)triphenylphosphinenickel(II)

Guidance literature:: In tetrahydrofuran; hexane; byproducts: LiCl; soln. of complex in THF at -40°C was treated with 1 equiv of LiCH2SCH3 in hexane, soln. was slowly warmed to room temp. over 1 h (N2); evapd., ppt. was extd. with ether, hexane was added, pt. was washed with hexane and dried under vac.; elem. anal.;
DOI:10.1021/om00126a007

Reference yield: 91.0%

: 96348-87-7
(η5-cyclopentadienyl)(η1-(thiomethoxy)methyl)triphenylphosphinenickel(II)

: 333-27-7
methyl trifluoromethanesulfonate

: 96348-99-1
Ni(C₅H₅)P(C₆H₅)3CH₂S(CH₃)2⁽¹⁺⁾*O₃SCF₃^(1-)

Guidance literature:: In benzene; soln. of complex in benzene was treated with CH3OSO2CF3 (N2); ppt. was filtered, crystd. from CH2Cl2-C6H6; elem. anal.;
DOI:10.1021/om00126a007