[Pd(C₆H₃NH₂-2-NO₂-5)Br(2,2'-bipyridine)]

Base Information

Chemical Name:[Pd(C₆H₃NH₂-2-NO₂-5)Br(2,2'-bipyridine)]
CAS No.:399567-08-9
Molecular Formula:C₁₆H₁₃BrN₄O₂Pd
Molecular Weight:479.629
Hs Code.:

[Pd(C<sub>6</sub>H<sub>3</sub>NH<sub>2</sub>-2-NO<sub>2</sub>-5)Br(2,2'-bipyridine)]

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of [Pd(C₆H₃NH₂-2-NO₂-5)Br(2,2'-bipyridine)]

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Technology Process of [Pd(C₆H₃NH₂-2-NO₂-5)Br(2,2'-bipyridine)]

There total 1 articles about [Pd(C₆H₃NH₂-2-NO₂-5)Br(2,2'-bipyridine)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

: 366-18-7
[2,2]bipyridinyl

: Pd2(dba)4

: 13296-94-1
2-bromo-4-nitroaniline

: 399567-08-9
[Pd(C₆H₃NH₂-2-NO₂-5)Br(2,2'-bipyridine)]

Guidance literature:: In toluene; complex and bipyridine were mixed in toluene under N2, stirred for 15 min, 2-bromo-4-nitroaniline was added, stirred at 130°C for a few min; the solvent was removed in vac., extd. with acetone, filtered through MgSO4, evapd., diethyl ether was added, ppt. was washed with diethyl etherand dried in a current of air;
DOI:10.1021/om0104971

Reference yield: 75.0%

: 399567-08-9
[Pd(C₆H₃NH₂-2-NO₂-5)Br(2,2'-bipyridine)]

: 119072-54-7,2769-71-3
2,6-dimethylphenyl isonitrile

: 399567-18-1
trans-[Pd(C(=NC₆H₃Me₂-2,6)C₆H₄NH₂-2-NO₂-5)Br(CNC₆H₃Me₂-2,6)2]

Guidance literature:: In acetone; complex was reacted with isonitrile in acetone for 10 min; the solvent was evapd. in vac., diethyl ether was added, ppt. was filtered, washed with diethyl ether and n-hexane, air-dried;
DOI:10.1021/om0104971

Reference yield: 74.0%

: 399567-08-9
[Pd(C₆H₃NH₂-2-NO₂-5)Br(2,2'-bipyridine)]

: 119072-55-8,7188-38-7
tert-butylisonitrile

: 399567-11-4
trans-[Pd(C(=NBu-t)C₆H₄NH₂-2-NO₂-5)Br(CNBu-t)2]

Guidance literature:: In acetone; complex was reacted with isonitrile in acetone for 10 min; the solvent was evapd. in vac., diethyl ether was added, ppt. was filtered, washed with diethyl ether and n-hexane, air-dried;
DOI:10.1021/om0104971