1-methylthio-1'-phenylthioferrocene

Base Information

Chemical Name:1-methylthio-1'-phenylthioferrocene
CAS No.:676258-51-8
Molecular Formula:C₁₇H₁₆FeS₂
Molecular Weight:340.293
Hs Code.:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 1-methylthio-1'-phenylthioferrocene

Chemical Property:

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Technology Process of 1-methylthio-1'-phenylthioferrocene

There total 2 articles about 1-methylthio-1'-phenylthioferrocene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 30.0%

: 676258-43-8
bis(1'-methylthiolatoferrocenylene)disulfane

: 591-51-5
phenyllithium

: 676258-51-8
1-methylthio-1'-phenylthioferrocene

Guidance literature:: In tetrahydrofuran; diethyl ether; cyclohexane; PhLi in cyclohexane-ether was added at -78°C under inert atm. to a THF soln. of Fe-complex, soln. was allowed to warm to room temp., stirred for 20 h; the reaction was exposed to air, evapd., residue was dissolved in CH2Cl2, extd. with water, aq. layer was extd. with CH2Cl2, combined org. exts.were dried over MgSO3, evapd., residue was chromd. (Al2O3, 7:3 hexane-C H2Cl2); elem. anal.;
DOI:10.1021/om034287v

Reference yield:

: 1,2,3-trithia{3}ferrocenophane

: 591-51-5
phenyllithium

: 74-88-4
methyl iodide

: 1,1′-di(methylthio)ferrocene

: 1,1’-bis(phenylthio)ferrocene

: 676258-51-8
1-methylthio-1'-phenylthioferrocene

Guidance literature:: In tetrahydrofuran; diethyl ether; cyclohexane; PhLi in 7:3 cyclohexane-ether was added at -78°C under inert atm.to a THF soln. of Fe-complex, soln. was allowed to warm to room temp., stirred for 20 h, a THF soln. of MeI was added, stirred for 20 h; Me,Ph- to Me2- to Ph2-derivs. ratio 63:33:4; evapd., residue was redissolved in CH2Cl2, soln. washed with water, the exts. were further washed with CH2Cl2, the combined org. exts. were dried over MgSO4, evapd., chromd. on alumina (eluent 9:1 hexane-CH2Cl2): (1)NMr data;
DOI:10.1021/om034287v

Reference yield: 75.0%

: 14873-63-3,15617-19-3,51921-56-3
bis(benzonitrile)dichloroplatinum(II)

: 676258-51-8
1-methylthio-1'-phenylthioferrocene

: 676258-59-6
(1-methylthio-1'-phenylthioferrocene)platinum dichloride

Guidance literature:: In toluene; a toluene soln. of Fe-complex was added at 60°C to a soln. of Pt-complex in toluene, the mixt. was stirred for 20 h; cooled, ppt. was filtd., washed with hot hexane, Et2O, dried in vacuo for 1 h; elem. anal.;
DOI:10.1021/om034287v