Ir(acetylacetonato)(6-bromo-2,4-diphenylquinoline(-1H))2

Base Information

• Chemical Name: Ir(acetylacetonato)(6-bromo-2,4-diphenylquinoline(-1H))2
• CAS No.: 911383-08-9
• Molecular Formula: C₄₇H₃₃Br₂IrN₂O₂
• Molecular Weight: 1009.82
• Mol file: 911383-08-9.mol

Synonyms:

Chemical Property of Ir(acetylacetonato)(6-bromo-2,4-diphenylquinoline(-1H))2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Ir(acetylacetonato)(6-bromo-2,4-diphenylquinoline(-1H))2

There total 1 articles about Ir(acetylacetonato)(6-bromo-2,4-diphenylquinoline(-1H))2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

iridium(III) chloride trihydrate + acetylacetone (123-54-6,81235-32-7) + 6-bromo-2,4-diphenylquinoline (73402-93-4) → Ir(acetylacetonato)(6-bromo-2,4-diphenylquinoline(-1H))2 (911383-08-9)

Guidance literature:

With Na₂CO₃; In 2-ethoxy-ethanol; water; under Ar; ligand and IrCl3*3H2O in EtOC2H4OH-H2O stirred (120°C, 24 h); cooled to room temp.; filtered; ppt. washed (H2O, EtOH, hexane); dried in vac.; mixed with acetylacetone and Na2CO3; dissolved in EtOC2H4OH; stirred (100°C, 16 h); cooled to room temp.; filtered; ppt. washed with H2O, EtOH and hexane; flash chromd. (silica gel, CH2Cl2); elem. anal.;

DOI:10.1016/j.jorganchem.2006.07.008

upstream raw materials:

acetylacetone

6-bromo-2,4-diphenylquinoline