bis[dicyclohexylphosphinomethyl-methyl-pyridin-2-ylamine]palladium dichloride

Base Information

• Chemical Name: bis[dicyclohexylphosphinomethyl-methyl-pyridin-2-ylamine]palladium dichloride
• CAS No.: 959398-27-7
• Molecular Formula: C₃₈H₆₂Cl₂N₄P₂Pd
• Molecular Weight: 814.211
• Mol file: 959398-27-7.mol

Synonyms:

Chemical Property of bis[dicyclohexylphosphinomethyl-methyl-pyridin-2-ylamine]palladium dichloride

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of bis[dicyclohexylphosphinomethyl-methyl-pyridin-2-ylamine]palladium dichloride

There total 1 articles about bis[dicyclohexylphosphinomethyl-methyl-pyridin-2-ylamine]palladium dichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 26.0%

dicyclohexylphosphinomethyl-methyl-pyridin-2-ylamine (959398-22-2) + dichloro(1,5-cyclooctadiene)palladium(II) (12107-56-1) → bis[dicyclohexylphosphinomethyl-methyl-pyridin-2-ylamine]palladium dichloride (959398-27-7)

Guidance literature:

In dichloromethane; (under N2, Schlenk); soln. of Pd-complex added to flask, CH2Cl2 added, stirred, soln. transferred into flask with ligand at -10°C, stirred at 40°C overnight; solvent removed in vacuo, CH2Cl2 layered with Et2O; elem. anal.;

DOI:10.1039/b709032c

Reference yield: 72.0%

bis[dicyclohexylphosphinomethyl-methyl-pyridin-2-ylamine]palladium dichloride (959398-27-7) + silver perchlorate → (C5H4N2CH3CH2P(C6H11)2)2Pd(2+)*2ClO4(1-)=C38H62Cl2N4O8P2Pd

Guidance literature:

In dichloromethane; byproducts: AgCl; (under N2, Schlenk); AgClO4 added to soln. of Pd-complex in CH2Cl2, stirred for 48 h at room temp. in dark; filtered, evapd. to dryness, 2 d, CH2Cl2 layered with benzene, ppt. collected, filtered, washed with Et2O, dried in vacuo; elem. anal.;

DOI:10.1039/b709032c

upstream raw materials:

dicyclohexylphosphinomethyl-methyl-pyridin-2-ylamine

dichloro(1,5-cyclooctadiene)palladium(II)