2-(1-Benzyl-3-methyl-but-2-enylsulfanyl)-pyridine

Base Information

• Chemical Name: 2-(1-Benzyl-3-methyl-but-2-enylsulfanyl)-pyridine
• CAS No.: 35938-53-5
• Molecular Formula: C₁₇H₁₉NS
• Molecular Weight: 269.411
• Mol file: 35938-53-5.mol

Synonyms:

Chemical Property of 2-(1-Benzyl-3-methyl-but-2-enylsulfanyl)-pyridine

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of 2-(1-Benzyl-3-methyl-but-2-enylsulfanyl)-pyridine

There total 1 articles about 2-(1-Benzyl-3-methyl-but-2-enylsulfanyl)-pyridine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

→ 2-(1-Benzyl-3-methyl-but-2-enylsulfanyl)-pyridine (35938-53-5)

Guidance literature:

Pyridylsulfid (III), Bu-Li, Benzylbromid;

DOI:10.1246/cl.1972.259

Reference yield: 38.0%

2-(1-Benzyl-3-methyl-but-2-enylsulfanyl)-pyridine (35938-53-5) + tri-n-butyltin lithium (4226-01-1) → (CH3)2CCHCH(tributylstannyl)CH2Ph (117785-56-5)

Guidance literature:

With copper(I) bromide; lithium bromide; In tetrahydrofuran; addn. of a soln. of tributylstannyllithium in THF to a mixt. of the thiobutene and CuBr in THF at 0°C under Ar with stirring for 22.5 h; quenching with phosphate buffer soln. (pH 7), extn. with CH2Cl2, drying over Na2SO4, concg. under reduced pressure, chromy. on silica gel (hexane), IR, NMR;

DOI:10.1246/cl.1987.1967

Downstream raw materials:

(CH₃)2CCHCH(tributylstannyl)CH₂Ph