1-[diphenyl(trimethylsilylmethyl)stannyl]-3-(triphenylstannyl)propane

Base Information

• Chemical Name: 1-[diphenyl(trimethylsilylmethyl)stannyl]-3-(triphenylstannyl)propane
• CAS No.: 329735-89-9
• Molecular Formula: C₃₇H₄₂SiSn₂
• Molecular Weight: 752.246
• Mol file: 329735-89-9.mol

Synonyms:

Chemical Property of 1-[diphenyl(trimethylsilylmethyl)stannyl]-3-(triphenylstannyl)propane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-[diphenyl(trimethylsilylmethyl)stannyl]-3-(triphenylstannyl)propane

There total 1 articles about 1-[diphenyl(trimethylsilylmethyl)stannyl]-3-(triphenylstannyl)propane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(3-chloropropyl)diphenyl(trimethylsilylmethyl)tin (192998-31-5) + hexaphenylditin (1064-10-4) → 1-[diphenyl(trimethylsilylmethyl)stannyl]-3-(triphenylstannyl)propane (329735-89-9)

Guidance literature:

With napthalene; Na; In tetrahydrofuran; byproducts: NaCl; to soln. of (Ph3Sn)2 and naphthalene in THF Na was added in small portions; after 18 h stiriing to intermediate Ph3SnNa Cl(CH2)3Sn(Ph2)CH2SiMe3 was added dropwise at -50°C; 48 h stirring which time it was warmed up; dissolved in hot hexane; filtered; solv. removed in vac.;

DOI:10.1002/1099-0682(20011)2001:1<153::aid-ejic153>3.0.co;2-m

Reference yield: 53.0%

1-[diphenyl(trimethylsilylmethyl)stannyl]-3-(triphenylstannyl)propane (329735-89-9) → (C6H5)SnCl2(CH2)3Sn(Cl)2CH2Si(CH3)3 (329735-90-2)

Guidance literature:

With HgCl₂; In acetone; byproducts: C6H5HgCl; to soln. of Ph3Sn(CH2)3Sn(Ph2)CH2SiMe3 soln. of HgCl2 in Me2CO was addeddropwise at 0°C; suspn. stirred overnight; filtered; evapd. in vac.; suspended in Et2O; filtered; evapd.; solid extd. (hexane) in Soxhlet app. for 72 h; elem. anal.;

DOI:10.1002/1099-0682(20011)2001:1<153::aid-ejic153>3.0.co;2-m

Reference yield:

1-[diphenyl(trimethylsilylmethyl)stannyl]-3-(triphenylstannyl)propane (329735-89-9) → [(O2)(Sn(Cl)(CH2Si(CH3)3))2(CH2CH2CH2)2(Sn(Cl)(C6H5))2]2

Guidance literature:

Multi-step reaction with 2 steps

1: HgCl₂ / acetone

2: dichloromethane

With HgCl₂; In dichloromethane; acetone;

DOI:10.1002/1099-0682(20011)2001:1<153::aid-ejic153>3.0.co;2-m

upstream raw materials:

(3-chloropropyl)diphenyl(trimethylsilylmethyl)tin

hexaphenylditin

Downstream raw materials:

(C₆H₅)SnCl₂(CH₂)3Sn(Cl)2CH₂Si(CH₃)3