Hexaphenyldistannane

Base Information

• Chemical Name: Hexaphenyldistannane
• CAS No.: 1064-10-4
• Molecular Formula: C36H30 Sn2
• Molecular Weight: 700.054
• Hs Code.: 2931900090
• European Community (EC) Number: 213-902-6
• NSC Number: 22333
• UNII: 7MC26M1VE9
• DSSTox Substance ID: DTXSID4074439
• Mol file: 1064-10-4.mol

Synonyms:Hexaphenyldistannane;Hexaphenylditin;1064-10-4;1,1,1,2,2,2-Hexaphenyldistannane;Distannane, hexaphenyl-;Hexaphenylditin(IV);7MC26M1VE9;EINECS 213-902-6;MFCD00014070;NSC 22333;NSC-22333;AI3-51835;TIN, HEXAPHENYLDI-;Hexaphenylditin(IV), 97%;UNII-7MC26M1VE9;C36H30Sn2;DTXSID4074439;C36-H30-Sn2;UAPQJVJCJITJET-UHFFFAOYSA-N;NSC22333;AKOS024462604;1,1,1,2,2,2-Hexaphenyldistannane #;DISTANNANE, 1,1,1,2,2,2-HEXAPHENYL-;A895824

Chemical Property of Hexaphenyldistannane

Chemical Property:

• Melting Point: 233-237 °C(lit.)
• Boiling Point: 280°C
• Flash Point: °C
• PSA: 0.00000
• Density: g/cm³
• LogP: 4.40560
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 6
• Exact Mass: 700.03856
• Heavy Atom Count: 38
• Complexity: 457

Purity/Quality:

98%,99%, ^*data from raw suppliers

Hexaphenylditin, 99+% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: T,N
• Statements: 23/24/25-50/53
• Safety Statements: 26-27-28-45-60-61

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C1=CC=C(C=C1)[Sn](C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)[Sn](C2=CC=CC=C2)C3=CC=CC=C3

Technology Process of Hexaphenyldistannane

There total 184 articles about Hexaphenyldistannane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 20.0%

bis(triphenyltin) oxide (1262-21-1) → tetraphenyltin(IV) (595-90-4) + hexaphenylditin (1064-10-4)

Guidance literature:

With sodium; In neat (no solvent); stoich. amt. of sodium (2 mol for 1 mol of ditin oxide), 120°C, 48 h; Ph4Sn was the main product of the reaction; (119)Sn NMR analysis of the crude reaction mixt.;

DOI:10.1021/om00137a042

Reference yield:

triphenyltin chloride (639-58-7) + propargyl bromide (106-96-7) → hexaphenylditin (1064-10-4) + triphenylpropargyl stannane (4104-89-6,4104-90-9) + allenyltriphenylstannane (4104-90-9)

Guidance literature:

With ammonium chloride; zinc; In tetrahydrofuran; water; Ph3SnCl is added to THF/H2O (NH4Cl saturated) mixt. with excess of zinc powder, appropriate allyl bromide is added dropwise under stirring within 5 min, filtn. after 1 h of mixing, THF is removed, residue is treated with chloroform; extn. (chloroform), drying (Na2SO4), solvent is evapd., treated with petroleum ether or n-hexane, solvent is evapd., crystd. (ethanol), mixt. of Ph3SnCHCCH2 and Ph3SnCH2CCH ratio 58:42; total yield 74%;

DOI:10.1021/om00015a025

Reference yield:

phenyl thiocyanate (5285-87-0) + triphenylstannane (892-20-6) → hexaphenylditin (1064-10-4) + bis(triphenyltin) sulfide (77-80-5)

Guidance literature:

In not given; byproducts: C6H5NH2, C6H5NHCH3, C6H5NC;

DOI:10.1021/jo01041a508

upstream raw materials:

chloroform

2-monochlorophenol

triphenylstannyl radical

phenylmercury(II) chloride

Downstream raw materials:

(pentafluoroethyl)triphenylstannane

triphenylstannane

tetraphenyltin(IV)

triphenyltin chloride

Refernces

• 1、 Scoccia, Jimena,Gerbino, Darío César,Podestá, Julio César. "Synthesis of organotin derivatives of optically active eleven-membered macrodiolides". . p. 352 - 360. Retrieved 2016.
• 2、 Aruga, Tamotsu,Ito, Osamu,Matsuda, Minoru. "Formation and Decay of Radical Anions of Aromatic Compounds Produced by Photoinduced Electron Transfer from the Triphenylstannyl Anion". . p. 2950 - 2953. Retrieved 1982.
• 3、 Bumagin, N. A.,Gulevich, Yu. V.,Beletskaya, I. P.. "". . . Retrieved 1982.
• 4、 Gilman,Rosenberg. "-". . p. 531. Retrieved 1952.
• 5、 Habeeb,Tuck. "". . p. 363,366-368, 371-373. Retrieved 1977.
• 6、 Gilman,Gist. "-". . p. 689. Retrieved 1957.
• 7、 Hoidn, Christian M.,Wolf, Robert. "Reaction of a 2,4,6-triphenylphosphinine ferrate anion with electrophiles: A new route to phosphacyclohexadienyl complexes". . p. 8875 - 8884. Retrieved 2016.
• 8、 Liu, Liu Leo,Cao, Levy L.,Shao, Yue,Stephan, Douglas W.. "Single Electron Delivery to Lewis Pairs: An Avenue to Anions by Small Molecule Activation". . p. 10062 - 10071. Retrieved 2017.
• 9、 Rothman,Becker. "". . p. 2203,2205. Retrieved 1960.
• 10、 Braunstein, Pierre,Durand, Jér?me,Morise, Xavier,Tiripicchio, Antonio,Ugozzoli, Franco. "Catalytic dehydrogenative coupling of stannanes by alkoxysilyl heterobimetallic complexes: Influence of the assembling ligand". . p. 444 - 450. Retrieved 2000.