Technology Process of (3R,7R)-3,7-dimethyl-6-benzenesulfonylnonyl benzyl ether
There total 10 articles about (3R,7R)-3,7-dimethyl-6-benzenesulfonylnonyl benzyl ether which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
Multi-step reaction with 4 steps
1: 2 g / Pb(OAc)4, I2 / CCl4 / Heating; Irradiation
2: 1.) NaOEt / 1.) EtOH, 15 min., room temp., 2.) EtOH, room temp., 3 h
3: 2.93 g / MCPBA / CH2Cl2 / 2 h / Ambient temperature
4: 1.) n-BuLi / 1.) n-hexane, THF, HMPA, 15 min., -30 deg C 2.) THF, from -70 deg C to room temp., 2 h
With
lead(IV) acetate; n-butyllithium; iodine; sodium ethanolate; 3-chloro-benzenecarboperoxoic acid;
In
tetrachloromethane; dichloromethane;
DOI:10.1016/S0040-4020(01)91971-4
- Guidance literature:
-
Multi-step reaction with 3 steps
1: 1.) NaOEt / 1.) EtOH, 15 min., room temp., 2.) EtOH, room temp., 3 h
2: 2.93 g / MCPBA / CH2Cl2 / 2 h / Ambient temperature
3: 1.) n-BuLi / 1.) n-hexane, THF, HMPA, 15 min., -30 deg C 2.) THF, from -70 deg C to room temp., 2 h
With
n-butyllithium; sodium ethanolate; 3-chloro-benzenecarboperoxoic acid;
In
dichloromethane;
DOI:10.1016/S0040-4020(01)91971-4
- Guidance literature:
-
Multi-step reaction with 4 steps
1: 1.) ozone 2.) NaBH4 / 1.) CH2Cl2, MeOH, -70 deg C, 2.) room temperature, overnight
2: 5.72 g / pyridine / 5 h / 0 - 5 °C
3: 96 percent / NaI / acetone / reflux for 1.5 h then room temp. overnight
4: 1.) n-BuLi / 1.) n-hexane, THF, HMPA, 15 min., -30 deg C 2.) THF, from -70 deg C to room temp., 2 h
With
sodium tetrahydroborate; n-butyllithium; ozone; sodium iodide;
In
pyridine; acetone;
DOI:10.1016/S0040-4020(01)91971-4
