C₁₁H₁₀INO₄

Base Information

• Chemical Name: C₁₁H₁₀INO₄
• CAS No.: 1334223-42-5
• Molecular Formula: C₁₁H₁₀INO₄
• Molecular Weight: 347.109
• Mol file: 1334223-42-5.mol

Synonyms:

Chemical Property of C₁₁H₁₀INO₄

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₁₁H₁₀INO₄

There total 1 articles about C₁₁H₁₀INO₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(carbethoxymethyl)triphenylphosphonium bromide (1530-45-6) + 3-nitro-benzaldehyde (99-61-6) → C11H10INO4 (1334223-42-5)

Guidance literature:

(carbethoxymethyl)triphenylphosphonium bromide; With iodine; potassium carbonate; In methanol; at 0 - 5 ℃; for 1.5h; Inert atmosphere;

3-nitro-benzaldehyde; With tetrabutylammomium bromide; potassium carbonate; at 40 ℃; Inert atmosphere;

DOI:10.1002/anie.201103318

Reference yield:

C11H10INO4 (1334223-42-5) → C9H8INO3 (1334223-48-1)

Guidance literature:

With diisobutylaluminium hydride; In dichloromethane; at -78 ℃; for 3h; Inert atmosphere;

DOI:10.1002/anie.201103318

Reference yield:

C11H10INO4 (1334223-42-5) → C14H16INO4 (1334223-57-2)

Guidance literature:

Multi-step reaction with 2 steps

1: diisobutylaluminium hydride / dichloromethane / 3 h / -78 °C / Inert atmosphere

2: pyridinium p-toluenesulfonate / dichloromethane / 6 h / 20 °C / Inert atmosphere

With pyridinium p-toluenesulfonate; diisobutylaluminium hydride; In dichloromethane;

DOI:10.1002/anie.201103318

upstream raw materials:

(carbethoxymethyl)triphenylphosphonium bromide

3-nitro-benzaldehyde

Downstream raw materials:

C₉H₈INO₃

C₁₄H₁₆INO₄