[Ir(benzyl diphenylphosphine(-1H))2(3-trifluoromethyl-5-(2-pyridyl)pyrazolato)]

Base Information

Chemical Name:[Ir(benzyl diphenylphosphine(-1H))2(3-trifluoromethyl-5-(2-pyridyl)pyrazolato)]
CAS No.:1034708-56-9
Molecular Formula:C₄₇H₃₇F₃IrN₃P₂
Molecular Weight:954.994
Hs Code.:

Synonyms:

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Chemical Property of [Ir(benzyl diphenylphosphine(-1H))2(3-trifluoromethyl-5-(2-pyridyl)pyrazolato)]

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Technology Process of [Ir(benzyl diphenylphosphine(-1H))2(3-trifluoromethyl-5-(2-pyridyl)pyrazolato)]

There total 2 articles about [Ir(benzyl diphenylphosphine(-1H))2(3-trifluoromethyl-5-(2-pyridyl)pyrazolato)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 35.0%

: 35925-64-5,445022-31-1
trichlorotris(tetrahydrothiophene) iridium(III)

: 3974-71-8
3-trifluoromethyl-5-(2-pyridyl)pyrazole

: 7650-91-1
benzyldiphenylphosphane

: 1034708-56-9,1182732-97-3
[Ir(benzyl diphenylphosphine(-1H))2(3-trifluoromethyl-5-(2-pyridyl)pyrazolato)]

Guidance literature:: With Na₂CO₃; In decalin; (N2); decalin added to a mixt. of Ir complex and ligands, refluxed for 1h, Na2CO3 added, refluxed for 24 h; chromd. (silica gel, EtOAc/hexane), crystd. from EtOAc/hexane; elem. anal.;
DOI:10.1021/ic900607s

Reference yield: 15.0%

: iridium(III) trichloride hydrate

: 109-86-4,95507-80-5
2-methoxy-ethanol

: 3974-71-8
3-trifluoromethyl-5-(2-pyridyl)pyrazole

: 7650-91-1
benzyldiphenylphosphane

: 1034708-56-9,1182732-97-3
[Ir(benzyl diphenylphosphine(-1H))2(3-trifluoromethyl-5-(2-pyridyl)pyrazolato)]

: [Ir(benzyl diphenylphosphine(-1H))(3-trifluoromethyl-5-(2-pyridyl)pyrazolato)(benzyl diphenylphosphine)H]

: [Ir(benzyl diphenylphosphine(-1H))(3-trifluoromethyl-5-(2-pyridyl)pyrazolato)(benzyl diphenylphosphine)H]

: [Ir(benzyl diphenylphosphine(-1H))(3-trifluoromethyl-5-(2-pyridyl)pyrazolato)(benzyl diphenylphosphine)H]

Guidance literature:: With Na₂CO₃; In 2-methoxy-ethanol; (N2); 2-methoxyethanol added to Ir complex and C6H5CH2P(C6H5)2, refluxedfor 12 h, cooled to ambient temp., NC5H4C3H2N2CF3 and Na2CO3 added, ref luxed for 1 h; cooled to room temp., pptd. (H2O), filtered, washed (cold MeOH, Et2O), chromd. (silica gel, EtOAc/hexane), crystd. from a layered soln. of CH2Cl2 and hexane at room temp.; elem. anal.;
DOI:10.1021/ic900607s