C₂₆H₂₉F₃O₆S

Base Information

• Chemical Name: C₂₆H₂₉F₃O₆S
• CAS No.: 116384-37-3
• Molecular Formula: C₂₆H₂₉F₃O₆S
• Molecular Weight: 526.574
• Mol file: 116384-37-3.mol

Synonyms:

Chemical Property of C₂₆H₂₉F₃O₆S

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₂₆H₂₉F₃O₆S

There total 2 articles about C₂₆H₂₉F₃O₆S which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2,2,2-trifluoro-1,1-diphenylethane-sulfenyl chloride + 1,2:5,6-di-O-isopropylidene-α-D-glucofuranose (582-52-5) → C26H29F3O6S (116384-37-3)

Guidance literature:

With sodium hydride; In tetrahydrofuran; at 20 ℃;

DOI:10.1016/S0040-4039(00)80120-3

Reference yield:

1,2:5,6-di-O-isopropylidene-3-O-tosyl-α-D-glucofuranoside (3253-75-6) → C26H29F3O6S (116384-37-3)

Guidance literature:

Multi-step reaction with 2 steps

1: 15 percent / KO₂, 18C₆ / dimethylsulfoxide

2: NaH / tetrahydrofuran / 20 °C

With 18-crown-6 ether; sodium hydride; In tetrahydrofuran; dimethyl sulfoxide;

DOI:10.1016/S0040-4039(00)80120-3

Reference yield:

C26H29F3O6S (116384-37-3) → 2,2,2-Trifluoro-1,1-diphenyl-ethanesulfonic acid (3aR,5R,6S,6aR)-5-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yl ester (116408-84-5)

Guidance literature:

With sodium hydroxide; potassium permanganate; benzyltriethylammonium bromide; In tetrahydrofuran; water; at 20 ℃; for 2h; Yield given;

DOI:10.1016/S0040-4039(00)80120-3

upstream raw materials:

1,2:5,6-di-O-isopropylidene-α-D-glucofuranose

1,2:5,6-di-O-isopropylidene-3-O-tosyl-α-D-glucofuranoside

Downstream raw materials:

2,2,2-Trifluoro-1,1-diphenyl-ethanesulfonic acid (3aR,5R,6S,6aR)-5-((R)-1,2-dihydroxy-ethyl)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yl ester

2,2,2-Trifluoro-1,1-diphenyl-ethanesulfonic acid (3aR,5R,6S,6aR)-5-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yl ester

3-deoxy-1,2:5,6-di-O-isopropylidene-α-D-erythro-hex-3-enofuranose