D₃-1,3,5-tris(2-di(2'-pyridyl)hydroxymethylphenyl)benzene

Base Information

• Chemical Name: D₃-1,3,5-tris(2-di(2'-pyridyl)hydroxymethylphenyl)benzene
• CAS No.: 1272029-06-7
• Molecular Formula: C₅₇H₄₂N₆O₃
• Molecular Weight: 861.975
• Mol file: 1272029-06-7.mol

Synonyms:

Chemical Property of D₃-1,3,5-tris(2-di(2'-pyridyl)hydroxymethylphenyl)benzene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of D₃-1,3,5-tris(2-di(2'-pyridyl)hydroxymethylphenyl)benzene

There total 2 articles about D₃-1,3,5-tris(2-di(2'-pyridyl)hydroxymethylphenyl)benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 12.0%

2,2'-dipyridyl ketone (19437-26-4) + D3-1,3,5-tris(2-bromophenyl)benzene (1272029-05-6) → D3-1,3,5-tris(2-di(2'-pyridyl)hydroxymethylphenyl)benzene (1272029-06-7)

Guidance literature:

D₃-1,3,5-tris(2-bromophenyl)benzene; With tert.-butyl lithium; In hexanes; diethyl ether; at 20 ℃; for 0.166667h; Inert atmosphere; Cooling;

2,2'-dipyridyl ketone; In tetrahydrofuran; hexanes; diethyl ether; at 20 ℃; for 7h; Inert atmosphere; Cooling;

DOI:10.1002/anie.201005232

Reference yield:

2-bromophenyl methyl ketone (2142-69-0) → D3-1,3,5-tris(2-di(2'-pyridyl)hydroxymethylphenyl)benzene (1272029-06-7)

Guidance literature:

Multi-step reaction with 3 steps

1.1: water-d2; sodium hydroxide / 40 h / 20 °C / Inert atmosphere

2.1: trifluorormethanesulfonic acid / 14 h / 130 °C / Inert atmosphere

3.1: tert.-butyl lithium / hexanes; diethyl ether / 0.17 h / 20 °C / Inert atmosphere; Cooling

3.2: 7 h / 20 °C / Inert atmosphere; Cooling

With trifluorormethanesulfonic acid; water-d2; tert.-butyl lithium; sodium hydroxide; In hexanes; diethyl ether;

DOI:10.1002/anie.201005232

upstream raw materials:

2,2'-dipyridyl ketone

D₃-1,3,5-tris(2-bromophenyl)benzene

2-bromophenyl methyl ketone