bis[1,2-bis(diphenylphosphine)ethane]ruthenium dichloride

Base Information

• Chemical Name: bis[1,2-bis(diphenylphosphine)ethane]ruthenium dichloride
• CAS No.: 123931-99-7
• Molecular Formula: C₅₂H₄₈Cl₂P₄Ru
• Molecular Weight: 968.824
• Mol file: 123931-99-7.mol

Synonyms:

Chemical Property of bis[1,2-bis(diphenylphosphine)ethane]ruthenium dichloride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of bis[1,2-bis(diphenylphosphine)ethane]ruthenium dichloride

There total 4 articles about bis[1,2-bis(diphenylphosphine)ethane]ruthenium dichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

bis[bis(diphenylphosphino)ethane-P,P'](styrene)ruthenium → bis[1,2-bis(diphenylphosphine)ethane]ruthenium dichloride (123931-99-7,16594-81-3,19349-72-5)

Guidance literature:

With chloroform; In chloroform; in CHCl3 under Ar at room temp.;

Reference yield:

tris(triphenylphosphine)ruthenium(II) chloride (15529-49-4,41756-81-4) + 1,2-bis-(diphenylphosphino)ethane (1663-45-2) → bis[1,2-bis(diphenylphosphine)ethane]ruthenium dichloride (123931-99-7,16594-81-3,19349-72-5)

Guidance literature:

In acetone; suspn. of Ru-compound in acetone mixed with organic ligand under Ar withfast stirring; precipitate sepd. after 2 min with suction filter after 10 min of stirring at room temp.; washed with acetone, methanol; dried in vacuum; elem. anal.;

DOI:10.1016/j.jcat.2004.09.026

Reference yield:

[RuCl2(P(t)Bu2Cy)]3 (871313-88-1) + 1,2-bis-(diphenylphosphino)ethane (1663-45-2) → bis[1,2-bis(diphenylphosphine)ethane]ruthenium dichloride (123931-99-7,16594-81-3,19349-72-5)

Guidance literature:

In not given;

DOI:10.1021/om050649i

upstream raw materials:

tris(triphenylphosphine)ruthenium(II) chloride

1,2-bis-(diphenylphosphino)ethane

[RuCl₂(P(t)Bu₂Cy)]3

Downstream raw materials:

{trans-Ru(1,2-bis(diphenylphosphino)ethane)2(CO)Cl}Cl

[RuCl(dppe)₂]PF₆