(cyclohexyl)C(N-2,6-Me₂C₆H₃)2H

Base Information

• Chemical Name: (cyclohexyl)C(N-2,6-Me₂C₆H₃)2H
• CAS No.: 1158184-57-6
• Molecular Formula: C₂₃H₃₀N₂
• Molecular Weight: 334.505
• Mol file: 1158184-57-6.mol

Synonyms:

Chemical Property of (cyclohexyl)C(N-2,6-Me₂C₆H₃)2H

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (cyclohexyl)C(N-2,6-Me₂C₆H₃)2H

There total 1 articles about (cyclohexyl)C(N-2,6-Me₂C₆H₃)2H which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

2,6-dimethylaniline (87-62-7) + Cyclohexanecarboxylic acid (98-89-5) → (cyclohexyl)C(N-2,6-Me2C6H3)2H (1158184-57-6)

Guidance literature:

With polyphosphoric acid trimethylsilyl ester; at 180 ℃; for 8h; Inert atmosphere;

DOI:10.1016/j.jorganchem.2008.12.014

Reference yield: 87.0%

n-butyllithium (109-72-8,29786-93-4) + (cyclohexyl)C(N-2,6-Me2C6H3)2H (1158184-57-6) + sodium hexamethyldisilazane (1070-89-9) + neodymium trichloride (10024-93-8) → [neodymium(III)((cyclohexyl)C(N-2,6-Me2C6H3)2)2(N(SiMe3)2)] (1257082-53-3)

Guidance literature:

In tetrahydrofuran; hexane; Ar, Schlenk technique; n-BuLi (1mmol) (in hexane) added to (CyC(N-2,6-Me2C6H3)2)H (1 mmol) (THF) soln. at room temp., after 15 min mixt. added to NdCl3 (0.5 mmol) (THF), stirred (room temp., 2 h), NaN(SiMe3)2 (0.5 mmol) added, stirred (4 h, room temp.); solvent removed under vac., washed with hexane, residue extracted by toluene, volatiles removed, recrystd. from hexane/THF; elem. anal.;

DOI:10.1016/j.ica.2010.07.036

Reference yield: 86.0%

bis(tetrahydrofuran)tris(trimethylsilylmethyl)yttrium(III) + (cyclohexyl)C(N-2,6-Me2C6H3)2H (1158184-57-6) → [(CyC(N-2,6-Me2C6H3)2Y(CH2SiMe3)2(THF)2] (1158184-60-1)

Guidance literature:

In tetrahydrofuran; (Ar, Schlenk and glovebox) to a THF soln. of complex an amidinate-compound in THF was added dropwise at room temp., the mixt. was stirred at room temp. for 4 h; the solvent was removed under reduced pressure, the powder was washed with hexane and dried; elem. anal.;

DOI:10.1016/j.jorganchem.2008.12.014

upstream raw materials:

2,6-dimethylaniline

Cyclohexanecarboxylic acid

Downstream raw materials:

[(CyC(N-2,6-Me₂C₆H₃)2Lu(CH₂SiMe₃)2(THF)2]

[(CyC(N-2,6-Me₂C₆H₃)2Y(CH₂SiMe₃)2(THF)2]

[(CyC(N-2,6-iPr₂C₆H₃)2Nd(CH₂SiMe₃)2(THF)2]

[neodymium(III)((cyclohexyl)C(N-2,6-Me₂C₆H₃)2)2(N(SiMe₃)2)]