{(tetraphenylporphyrinato)(S)vanadium(IV)}

Base Information

• Chemical Name: {(tetraphenylporphyrinato)(S)vanadium(IV)}
• CAS No.: 85961-82-6
• Molecular Formula: C₄₄H₂₈N₄SV
• Molecular Weight: 695.741
• Mol file: 85961-82-6.mol

Synonyms:

Chemical Property of {(tetraphenylporphyrinato)(S)vanadium(IV)}

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of {(tetraphenylporphyrinato)(S)vanadium(IV)}

There total 2 articles about {(tetraphenylporphyrinato)(S)vanadium(IV)} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 45.0%

{(tetrahydrofurane)2(tetraphenylporphyrinato)vanadium(IV)}= (85961-84-8) + sulfur (7704-34-9) → {(tetraphenylporphyrinato)(S)vanadium(IV)} (85961-82-6)

Guidance literature:

In tetrahydrofuran; stirring under Ar for 5 h at room temp.; concn., removing of S by sublimation (110-120°C, 0.1 mm Hg), chromy. on alumina (toluene); recrystn. from toluene/heptane;

DOI:10.1016/S0277-5387(00)83940-6

Reference yield:

sulfur (10544-50-0) + tetraphenylporphyrinatovanadium(IV) dichloride (83582-00-7) → {(tetraphenylporphyrinato)(S)vanadium(IV)} (85961-82-6)

Guidance literature:

With Zn#Hg; In tetrahydrofuran; (under Ar); stirring of the chloro-complex in THF with Zn#Hg yields the THF-complex for 24 h, addn. of sulphur after sepg. from the amalgame, stirring for 5 h at room temp.; not pure isolated;

upstream raw materials:

{(tetrahydrofurane)2(tetraphenylporphyrinato)vanadium(IV)}=

sulfur

sulfur

tetraphenylporphyrinatovanadium(IV) dichloride