83582-00-7

Upstream product

• 14705-63-6 oxovanadium(IV) tetraphenylporphyrin 
• 79-37-8 oxalyl dichloride 
• 7719-09-7 thionyl chloride 
• 14705-63-6 oxovanadium(IV) tetraphenylporphyrin 

Downstream Products

• 85961-82-6 {(tetraphenylporphyrinato)(S)vanadium(IV)} 
• 95246-97-2 {(tetraphenylporphyrinato)(Se)vanadium(IV)} 
• 1322563-22-3 5,10,15,20-tetraphenylporphyrinatovanadium(IV) trifluoromethanesulfonate 
• 85961-84-8 {(tetrahydrofurane)2(tetraphenylporphyrinato)vanadium(IV)}= 

Relevant academic research and scientific papers

Highly efficient tetrahydropyranylation of alcohols and phenols catalyzed by a new and reusable high-valent vanadium(IV) porphyrin

In the present work, the catalytic activity of high-valent tetraphenylporphyrinatovanadium(IV) trifluoromethanesulfonate, [V IV(TPP)(OTf)2], in the tetrahydropyranylation of alcohols and phenols with 3,4-dihydro-2H-pyran (DHP) is reported. This new electron-deficient V(IV) compound was used as a highly efficient catalyst for pyranylation of primary (aliphatic and benzylic), sterically-hindered secondary and tertiary alcohols with DHP. Tetrahydropyranylation of phenols with DHP was also performed to afford the desired THP-ethers. The chemoselectivity of this method was also investigated. The results indicated that primary alcohols are more reactive in the presence of secondary and tertiary alcohols and phenols. This catalyst was reused several times without loss of its activity.

Investigation of the catalytic activity of an electron-deficient vanadium(IV) tetraphenylporphyrin: A new, highly efficient and reusable catalyst for ring-opening of epoxides

In this work, the catalytic activity of high-valent tetraphenylporphyrinatovanadium(IV) trifluoromethanesulfonate, [V IV(TPP)(OTf)2], in the nucleophilic ring-opening of epoxides is reported. This new V(IV) catalyst was used as an efficient catalyst for alcoholysis with primary (methanol, ethanol and n-propanol), secondary (iso-propanol) and tertiary alcohols (tert-butanol), hydrolysis and acetolysis of epoxides with acetic acid and also for the conversion of epoxides to 1,2-diacetates with acetic anhydride, conversion of epoxides to thiiranes with ammonium thiocyanate and thiourea, and for conversion of epoxides to acetonides with acetone. The catalyst was reused several times without loss of its activity.

Investigation of catalytic activity of high-valent vanadium(IV) tetraphenylporphyrin: A new, highly efficient and reusable catalyst for acetylation of alcohols and phenols with acetic anhydride

In the present work, the catalytic activity of high-valent tetraphenylporphyrinatovanadium(IV) trifluoromethanesulfonate, [V IV(TPP)(OTf)2], in the acetylation of alcohols and phenols with Ac2O is reported. This new V(IV) catalyst was used as an efficient catalyst for not only primary alcohols (benzylic and aliphatic) but also sterically-hindered secondary and tertiary alcohols with acetic anhydride and the corresponding acetates were obtained in 85-99% yield and 0.5-15 min. Acetylation of phenols with acetic anhydride was also performed to afford the desired acetates in 88-99% and 1.5-20 min. This catalyst can be reused several times without loss of its catalytic activity.

Electron-deficient vanadium(IV) tetraphenylporphyrin: A new, highly efficient and reusable catalyst for chemoselective trimethylsilylation of alcohols and phenols with hexamethyldisilazane

In the present work, the application of electron-deficient tetraphenylporphyrinatovanadium(IV) trifluoromethanesulfonate, [V IV(TPP)(OTf)2], in the trimethylsilylation of alcohols and phenols with hexamethydisilazane (HMDS) is reported. This new V(IV) catalyst was used as an efficient catalyst for silylation of not only primary alcohols but also sterically hindered secondary and tertiary alcohols with HMDS. Trimethylsilylation of phenols with HMDS was also performed to afford the desired Trimethylsilyl ethers (TMS) ethers. The chemoselectivity of this method was also investigated. This catalyst can be reused several times without loss of its activity. Copyright

Vanadium(IV) Porphyrins: Syntyhesis and Spectrochemical Characterization of Dihalogenovanadium(IV) Porphyrins. Extended X-Ray Absorption Fine Structural Study of Dibromo(2,3,7,8,12,13,17,18-octaethylporphyrinato)vanadium(IV)

The action of SOX2 or (COX)2 on oxovanadium(IV) porphyrin complexes (L=porphyrinate) under mild conditions affords the corresponding dihalogenovanadium(IV) porphyrins (X=Cl or Br).These very reactive complexes are remarkable precurs