(1-ethynyl-1-cylohexanol)dicobalt hexacarbonyl

Base Information

• Chemical Name: (1-ethynyl-1-cylohexanol)dicobalt hexacarbonyl
• CAS No.: 40747-46-4
• Molecular Formula: C₁₄H₁₂Co₂O₇
• Molecular Weight: 410.231
• Mol file: 40747-46-4.mol

Synonyms:

Chemical Property of (1-ethynyl-1-cylohexanol)dicobalt hexacarbonyl

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of (1-ethynyl-1-cylohexanol)dicobalt hexacarbonyl

There total 2 articles about (1-ethynyl-1-cylohexanol)dicobalt hexacarbonyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

dicobalt octacarbonyl (15226-74-1,61091-28-9,61117-58-6) + 1-Ethynylcyclohexan-1-ol (78-27-3) → Co3(CO)9[μ3-CCH2(C6H10OH)] + (1-ethynyl-1-cylohexanol)dicobalt hexacarbonyl (40747-46-4)

Guidance literature:

In benzene; ligand added under N2 to a soln. of metal carbonyl; refluxed for 4-5 minand allowed to cool to room temp.; TLC chromy. on Kieselgel; elem. anal.;

DOI:10.1039/b101119g

Reference yield: 5.0%

triiron dodecarbonyl (17685-52-8) + dicobalt octacarbonyl (15226-74-1,61091-28-9,61117-58-6) + 1-Ethynylcyclohexan-1-ol (78-27-3) → Co3(CO)9[μ3-CCH2(C6H10OH)] + (1-ethynyl-1-cylohexanol)dicobalt hexacarbonyl (40747-46-4) + Fe2(CO)6((CH)2C2(C6H10OH)2) + Fe2(CO)6((CH)2C2(C6H10OH)2) + Fe3(CO)7[μ3-η(7)-(C6H10OH)CCHCHC(C6H9)]

Guidance literature:

In toluene; ligand added under N2 to a soln. of Co carbonyl in toluene, refluxed for2 min, Fe carbonyl added, refluxed for 6 min; TLC chromy. on Kieselgel; elem. anal.; single crystal X-ray diffraction;

DOI:10.1039/b101119g

upstream raw materials:

dicobalt octacarbonyl

1-Ethynylcyclohexan-1-ol

triiron dodecarbonyl