trans-diiodo-(2,3,5-trimethyl-1-phenylpyrazolin-4-ylidene)(pyridine)palladium(II)

Base Information

Chemical Name:trans-diiodo-(2,3,5-trimethyl-1-phenylpyrazolin-4-ylidene)(pyridine)palladium(II)
CAS No.:1149362-15-1
Molecular Formula:C₁₇H₁₉I₂N₃Pd
Molecular Weight:625.587
Hs Code.:

Synonyms:

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Chemical Property of trans-diiodo-(2,3,5-trimethyl-1-phenylpyrazolin-4-ylidene)(pyridine)palladium(II)

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Technology Process of trans-diiodo-(2,3,5-trimethyl-1-phenylpyrazolin-4-ylidene)(pyridine)palladium(II)

There total 2 articles about trans-diiodo-(2,3,5-trimethyl-1-phenylpyrazolin-4-ylidene)(pyridine)palladium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 110-86-1
pyridine

: tris(dibenzylideneacetone)dipalladium ⁽⁰⁾

: 1204337-12-1
4-iodo-2,3,5-trimethyl-1-phenylpyrazolium iodide

: 1149362-15-1
trans-diiodo-(2,3,5-trimethyl-1-phenylpyrazolin-4-ylidene)(pyridine)palladium(II)

Guidance literature:: In dichloromethane; under N2; Pd-contg. compd. (0.27 mmol) and pyridine (1.09 mmol) were dissolved in dry CH2Cl2 and stirred at ambient temp. for 10 min; to the resulting soln. was added a soln. of a ligand (0.54 mmol) in dry CH2Cl2; heating under reflux for 6 h, cooling; the mixt. was filtered through Celite and the filtrate was extd. with H2O; the CH2Cl2 layer was dried over Na2SO4; the solvent was removed undervac.; the residue was washed with hexane and recrystd. by slow evapn. o f concd. acetone soln.; elem. anal.;
DOI:10.1021/om8010849

Reference yield: 48.0%

: 110-86-1
pyridine

: tris(dibenzylideneacetone)dipalladium ⁽⁰⁾

: 1149362-03-7
4-iodo-2,3,5-trimethyl-1-phenyl-1H-pyrazol-2-ium tetrafluoroborate

: 1149362-15-1
trans-diiodo-(2,3,5-trimethyl-1-phenylpyrazolin-4-ylidene)(pyridine)palladium(II)

Guidance literature:: In dichloromethane; under N2; Pd-contg. compd. (0.27 mmol) and pyridine (1.09 mmol) were dissolved in dry CH2Cl2 and stirred at ambient temp. for 10 min; to the resulting soln. was added a soln. of a ligand (0.54 mmol) in dry CH2Cl2; heating under reflux for 6 h, cooling; the mixt. was filtered through Celite and the filtrate was extd. with H2O; the CH2Cl2 layer was dried over Na2SO4; the solvent was removed undervac.; the residue was washed with hexane and recrystd. by slow evapn. o f concd. acetone soln.;
DOI:10.1021/om8010849