10,10',15,15'-tetrakis(3,5-di-tert-butylphenyl) Zn(II) diporphyrin

Base Information

• Chemical Name: 10,10',15,15'-tetrakis(3,5-di-tert-butylphenyl) Zn(II) diporphyrin
• CAS No.: 832079-42-2
• Molecular Formula: C₉₆H₁₀₂N₈Zn₂
• Molecular Weight: 1498.7
• Mol file: 832079-42-2.mol

Synonyms:

Chemical Property of 10,10',15,15'-tetrakis(3,5-di-tert-butylphenyl) Zn(II) diporphyrin

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 10,10',15,15'-tetrakis(3,5-di-tert-butylphenyl) Zn(II) diporphyrin

There total 7 articles about 10,10',15,15'-tetrakis(3,5-di-tert-butylphenyl) Zn(II) diporphyrin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 17.0%

{5,10-bis[3,5-di(tert-butyl)phenyl]porphyrinato-κN21,κN22,κN23,κN24}zinc(II) (832079-41-1) → [Zn2(((C5H2N)4H(C6H3(C(CH3)3)2)2)2)] (832079-42-2,832732-08-8,832732-12-4,1072782-64-9)

Guidance literature:

With AgPF₆; In chloroform; acetonitrile; soln. AgPF6 in MeCN was added to soln. Zn complex in CHCl3 and stirred at 5°C for 1 h in the dark; react. was stopped by washing with water, org. layer was dried over Na2SO4, solvent was removed in vacuo, chromy. on prep. size-exclusion column(CHCl3), recrystn. from CH2Cl2-hexane;

DOI:10.1021/ja0611137

Reference yield: 13.0%

(5,15-dibromo-10,20-di-n-butyl-porphyrin)zinc(II) (1072782-62-7) + 5,10-bis(3,5-di-t-butylphenyl)-15-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)porphyrin zinc(II) complex (1072782-61-6) → [Zn2(((C5H2N)4H(C6H3(C(CH3)3)2)2)2)] (832079-42-2,832732-08-8,832732-12-4,1072782-64-9) + [((Zn(H(CC4H2N)4(C6H3(C(CH3)3)2)2))2(CC4H2N)4(C4H9)2)Zn] (1072782-63-8,1072959-16-0) + [((Zn(H(CC4H2N)4(C6H3(C(CH3)3)2)2))2(CC4H2N)4(C4H9)2)Zn] (1072959-16-0,1072782-63-8)

Guidance literature:

With Cs₂CO₃; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In N,N-dimethyl-formamide; toluene; 80°C for 2 h (Suzuki-Miyaura coupling); gel permeation chromy., chromy. (silica gel); NMR;

DOI:10.1039/b807351a

Reference yield: 2.3%

(5,15-dibromo-10,20-di-n-butyl-porphyrin)zinc(II) (1072782-62-7) + 5,10-bis(3,5-di-t-butylphenyl)-15-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)porphyrin zinc(II) complex (1072782-61-6) → [Zn2(((C5H2N)4H(C6H3(C(CH3)3)2)2)2)] (832732-08-8,832732-12-4,832079-42-2,1072782-64-9) + [((Zn(H(CC4H2N)4(C6H3(C(CH3)3)2)2))2(CC4H2N)4(C4H9)2)Zn] (1072782-63-8,1072959-16-0) + [((Zn(H(CC4H2N)4(C6H3(C(CH3)3)2)2))2(CC4H2N)4(C4H9)2)Zn] (1072959-16-0,1072782-63-8)

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; caesium carbonate; In N,N-dimethyl-formamide; toluene; at 80 ℃; for 20h; Inert atmosphere;

DOI:10.1039/b807351a

upstream raw materials:

{5,10-bis[3,5-di(tert-butyl)phenyl]porphyrinato-κN²¹,κN²²,κN²³,κN²⁴}zinc(II)

(5,15-dibromo-10,20-di-n-butyl-porphyrin)zinc(II)

5,10-bis(3,5-di-t-butylphenyl)-15-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)porphyrin zinc(II) complex

Downstream raw materials:

C₉₆H₁₀₀Br₂N₈Zn₂

(Zn(N₄C₂₀H₈(C₆H₃(C(CH₃)3)2)2NO₂))2

(Zn(N₄C₂₀H₈(C₆H₃(C(CH₃)3)2)2NO₂))2

C₁₉₂H₂₀₂N₁₆Zn₄