[(WCl(CO)2(1,2-bis(diphenylphosphino)ethane))2(C₄)]

Base Information

• Chemical Name: [(WCl(CO)2(1,2-bis(diphenylphosphino)ethane))2(C₄)]
• CAS No.: 1214913-57-1
• Molecular Formula: C₆₀H₄₈Cl₂O₄P₄W₂
• Molecular Weight: 1395.54
• Mol file: 1214913-57-1.mol

Synonyms:

Chemical Property of [(WCl(CO)2(1,2-bis(diphenylphosphino)ethane))2(C₄)]

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of [(WCl(CO)2(1,2-bis(diphenylphosphino)ethane))2(C₄)]

There total 2 articles about [(WCl(CO)2(1,2-bis(diphenylphosphino)ethane))2(C₄)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 51.0%

hexachloroethane (67-72-1) + Li2[(W(CO)3(1,2-bis(diphenylphosphino)ethane))2(butadiynediyl)]*3tetrahydrofuran*2benzene → [(WCl(CO)2(1,2-bis(diphenylphosphino)ethane))2(C4)] (1214913-57-1)

Guidance literature:

In tetrahydrofuran; 1,2-dimethoxyethane; (N2); addn. of THF soln. of C2Cl6 to soln. of tungsten compd. in glyme at room temp., stirring for 6 h; evapn., washing with CH3CN, drying in vac., elem. anal.;

DOI:10.1021/ja909764x

Reference yield: 15.0%

chloroform (67-66-3,8013-54-5) + Li2[(W(CO)3(1,2-bis(diphenylphosphino)ethane))2(butadiynediyl)]*3tetrahydrofuran*2benzene → [(WCl(CO)2(1,2-bis(diphenylphosphino)ethane))2(C4)] (1214913-57-1)

Guidance literature:

In diethylene glycol dimethyl ether; (N2); addn. of CHCl3 to soln. of tungsten compd. in diglyme, keeping at room temp.; evapn., chromy. (silica gel, benzene), evapn., washing with CH3CN, drying in vac., elem. anal.;

DOI:10.1021/ja909764x

upstream raw materials:

chloroform

hexachloroethane