(η(5)-diphenylphosphinylcyclopentadienyl)triisopropoxytitanium

Base Information

• Chemical Name: (η(5)-diphenylphosphinylcyclopentadienyl)triisopropoxytitanium
• CAS No.: 163927-78-4
• Molecular Formula: C₂₆H₃₅O₃PTi
• Molecular Weight: 474.416
• Mol file: 163927-78-4.mol

Synonyms:

Chemical Property of (η(5)-diphenylphosphinylcyclopentadienyl)triisopropoxytitanium

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (η(5)-diphenylphosphinylcyclopentadienyl)triisopropoxytitanium

There total 1 articles about (η(5)-diphenylphosphinylcyclopentadienyl)triisopropoxytitanium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

triisopropoxytitanium(IV) chloride (20717-86-6) + lithium diphenylphosphinocyclopentadienyl (83272-80-4) → (η(5)-diphenylphosphinylcyclopentadienyl)triisopropoxytitanium (163927-78-4)

Guidance literature:

In diethyl ether; inert atmosphere; slow addn. of Na-salt to equimolar amt. of Ti-compd. (ice-salt bath, 3 h), warming to room temp.; solvent removal (vac.), extn. into hexane, filtration (silica gel, Celite), solvent removal; elem. anal.;

DOI:10.1016/0022-328X(94)05160-D

Reference yield:

[ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2 (52462-29-0) + (η(5)-diphenylphosphinylcyclopentadienyl)triisopropoxytitanium (163927-78-4) → (C6H5)2PC5H4Ti(OCH(CH3)2)3RuCl2C6H4(CH3)CH(CH3)2 + (C5H5PPh2)RuCl2(p-cymene)

Guidance literature:

In not given;

DOI:10.1016/j.jorganchem.2004.09.021

upstream raw materials:

triisopropoxytitanium(IV) chloride

lithium diphenylphosphinocyclopentadienyl

Refernces

• 1、 Barry, Scot,Kucht, Andreas,Kucht, Homa,Rausch, Marvin D.. "Functionally substituted derivatives of (η5-cyclopentadienyl)triisopropoxytitanium and (η5-cyclopentadienyl)trichlorotitanium". . p. 195 - 200. Retrieved 2007/10/02.