rac-4-bromo[2.2]paracyclophan-13-ylenediphenylphosphine

Base Information

Chemical Name:rac-4-bromo[2.2]paracyclophan-13-ylenediphenylphosphine
CAS No.:727419-33-2
Molecular Formula:C₂₈H₂₄BrP
Molecular Weight:471.376
Hs Code.:

Synonyms:

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Chemical Property of rac-4-bromo[2.2]paracyclophan-13-ylenediphenylphosphine

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Technology Process of rac-4-bromo[2.2]paracyclophan-13-ylenediphenylphosphine

There total 1 articles about rac-4-bromo[2.2]paracyclophan-13-ylenediphenylphosphine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 196316-30-0,196316-31-1,23927-40-4,96392-77-7
4,16-dibromo[2.2]paracyclophane

: 1079-66-9,74391-44-9
chloro-diphenylphosphine

: 1062306-89-1,727419-33-2
rac-4-bromo[2.2]paracyclophan-13-ylenediphenylphosphine

Guidance literature:: 4,16-dibromo[2.2]paracyclophane; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 1h;

chloro-diphenylphosphine; In tetrahydrofuran; hexane; at -78 - 20 ℃;
DOI:10.1016/j.tetasy.2004.03.047

Reference yield: 70.0%

: 16523-54-9
chlorodicyclohexylphosphane

: 1062306-89-1,727419-33-2
rac-4-bromo[2.2]paracyclophan-13-ylenediphenylphosphine

: 1624314-97-1
rac-4-diphenylphosphino-12-dicyclohexylphosphino[2.2]paracyclophane

Guidance literature:: rac-4-bromo[2.2]paracyclophan-13-ylenediphenylphosphine; With tert.-butyl lithium; In tetrahydrofuran; pentane; at -78 ℃; for 1.5h; Inert atmosphere;

chlorodicyclohexylphosphane; In tetrahydrofuran; pentane; at -78 - 20 ℃; Inert atmosphere;
DOI:10.1002/ejoc.201400159

Reference yield: 68.0%

: 1121-60-4
pyridine-2-carbaldehyde

: 1062306-89-1,727419-33-2
rac-4-bromo[2.2]paracyclophan-13-ylenediphenylphosphine

: C₃₄H₃₀NOP

: C₃₄H₃₀NOP

Guidance literature:: rac-4-bromo[2.2]paracyclophan-13-ylenediphenylphosphine; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 1h;

pyridine-2-carbaldehyde; In tetrahydrofuran; hexane; at -78 - 20 ℃;
DOI:10.1021/jo801373r