[(E,s-trans-E)-(2-i-propyl)C₆H₄NC(methyl)C(methyl)NC₆H₄(2-i-propyl)]Rh(CO)I

Base Information

• Chemical Name: [(E,s-trans-E)-(2-i-propyl)C₆H₄NC(methyl)C(methyl)NC₆H₄(2-i-propyl)]Rh(CO)I
• CAS No.: 502640-67-7
• Molecular Formula: C₂₃H₂₈IN₂ORh
• Molecular Weight: 578.298
• Mol file: 502640-67-7.mol

Synonyms:

Chemical Property of [(E,s-trans-E)-(2-i-propyl)C₆H₄NC(methyl)C(methyl)NC₆H₄(2-i-propyl)]Rh(CO)I

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(E,s-trans-E)-(2-i-propyl)C₆H₄NC(methyl)C(methyl)NC₆H₄(2-i-propyl)]Rh(CO)I

There total 1 articles about [(E,s-trans-E)-(2-i-propyl)C₆H₄NC(methyl)C(methyl)NC₆H₄(2-i-propyl)]Rh(CO)I which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

[Rh(CO)2(μ-I)]2 + N,N'-bis(2-isopropylphenyl)butane-2,3-diimine (502640-74-6) → [(E,s-trans-E)-(2-i-propyl)C6H4NC(methyl)C(methyl)NC6H4(2-i-propyl)]Rh(CO)I (502640-67-7)

Guidance literature:

In tetrahydrofuran; N2; dropwise addn. THF soln. of ligand to THF soln. of Rh complex, stirring for 2 min; solvent removal under vac., drying in vac. for 24 h; elem. anal.;

DOI:10.1021/om020777w

Reference yield: 72.0%

[(E,s-trans-E)-(2-i-propyl)C6H4NC(methyl)C(methyl)NC6H4(2-i-propyl)]Rh(CO)I (502640-67-7) + methyl iodide (74-88-4) → [(E,s-trans-E)-(2-i-propyl)C6H4NC(methyl)C(methyl)NC6H4(2-i-propyl)]Rh(carbonyl)(methyl)I2

Guidance literature:

In dichloromethane; N2; addn of excess CH3I to dichloromethane soln. of Rh complex, stirringat room temp. for 1 h; solvent removal in vac., drying the solid under high vac.; elem. anal.;

DOI:10.1021/om020777w

Reference yield:

[(E,s-trans-E)-(2-i-propyl)C6H4NC(methyl)C(methyl)NC6H4(2-i-propyl)]Rh(CO)I (502640-67-7) + methyl iodide (74-88-4) → [(2,4,6-(methyl)3C6H2)NC(methyl)C(methyl)N(2,4,6-(methyl)3C6H2)]Rh(COCH3)I2 (502640-82-6)

Guidance literature:

In dichloromethane; N2;; not isolated, detected by IR; Kinetics;

DOI:10.1021/om020777w

upstream raw materials:

N,N'-bis(2-isopropylphenyl)butane-2,3-diimine

Downstream raw materials:

[(2,4,6-(methyl)3C₆H₂)NC(methyl)C(methyl)N(2,4,6-(methyl)3C₆H₂)]Rh(COCH₃)I₂