adamantyldiphenyltin bromide

Base Information

• Chemical Name: adamantyldiphenyltin bromide
• CAS No.: 96043-53-7
• Molecular Formula: C₂₂H₂₅BrSn
• Molecular Weight: 488.054
• Mol file: 96043-53-7.mol

Synonyms:

Chemical Property of adamantyldiphenyltin bromide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of adamantyldiphenyltin bromide

There total 1 articles about adamantyldiphenyltin bromide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

adamantyl triphenyltin (51533-75-6) + mercury dibromide → adamantyldiphenyltin bromide (96043-53-7)

Guidance literature:

In acetone; byproducts: phenylmercury(II) bromide; dissolving adamantyl triphenyltin (5 mmol) in acetone; treating with HgBr2 (5 mmol); refluxing for 4 h; cooling to room temp. (pptn. of phenylmercury(II) bromide);; filtering, evapg. filtrate in vac.; addn. of CH3OH, storing overnight at -15°C (crystn.); filtering off, extg. with CCl4; filtering, removing solvent; trituration with methanol at 0°C; elem. anal.;

DOI:10.1039/DT9930003085

Reference yield:

adamantyldiphenyltin bromide (96043-53-7) → adamantyldiphenyltin iodide (153360-22-6)

Guidance literature:

With I₂; In chloroform; cleavage with iodine;;

DOI:10.1039/DT9930003085

Reference yield:

adamantyldiphenyltin bromide (96043-53-7) + mercury(II) iodide → adamantyldiphenyltin iodide (153360-22-6)

Guidance literature:

In acetone; cleavage with HgI2;;

DOI:10.1039/DT9930003085

upstream raw materials:

adamantyl triphenyltin

Downstream raw materials:

adamantyldiphenyltin iodide