adamantyl triphenyltin

Base Information

• Chemical Name: adamantyl triphenyltin
• CAS No.: 51533-75-6
• Molecular Formula: C₂₈H₃₀Sn
• Molecular Weight: 485.256
• Mol file: 51533-75-6.mol

Synonyms:

Chemical Property of adamantyl triphenyltin

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of adamantyl triphenyltin

There total 1 articles about adamantyl triphenyltin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 19.0%

1-chloroadamantane (935-56-8) + triphenyltin chloride (639-58-7) → adamantyl triphenyltin (51533-75-6)

Guidance literature:

With sodium; In cyclohexane; refluxing, 6 h, N2;;

DOI:10.1016/S0022-328X(73)80028-2

Reference yield: 85.0%

adamantyl triphenyltin (51533-75-6) + mercury dibromide → adamantyldiphenyltin bromide (96043-53-7)

Guidance literature:

In acetone; byproducts: phenylmercury(II) bromide; dissolving adamantyl triphenyltin (5 mmol) in acetone; treating with HgBr2 (5 mmol); refluxing for 4 h; cooling to room temp. (pptn. of phenylmercury(II) bromide);; filtering, evapg. filtrate in vac.; addn. of CH3OH, storing overnight at -15°C (crystn.); filtering off, extg. with CCl4; filtering, removing solvent; trituration with methanol at 0°C; elem. anal.;

DOI:10.1039/DT9930003085

Reference yield: 75.0%

adamantyl triphenyltin (51533-75-6) → adamantyl(phenyl)tin dibromide (96043-52-6)

Guidance literature:

With Br₂; In tetrachloromethane; dissolving adamantyl triphenyltin (0.024 mol) in min. vol. of CCl4; treating with Br2 (0.048 mol) in CCl4 (1 M);; removal of solvent after 5 min; storing overnight at 0°C (crystn.); triturating with methanol and filtering off; recrystn. from methanol, drying; elem. anal.;

DOI:10.1039/DT9930003085

upstream raw materials:

1-chloroadamantane

triphenyltin chloride

Downstream raw materials:

adamantyl(phenyl)tin dibromide

adamantyldiphenyltin bromide

adamantyldiphenyltin iodide