[α-(η4-tetraphenylcyclobutadiene)cobalt(η5-cyclopentadienyl)]benzyl alcohol

Base Information

Chemical Name:[α-(η4-tetraphenylcyclobutadiene)cobalt(η5-cyclopentadienyl)]benzyl alcohol
CAS No.:182627-84-5
Molecular Formula:C₄₀H₃₁CoO
Molecular Weight:586.679
Hs Code.:

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Chemical Property of [α-(η4-tetraphenylcyclobutadiene)cobalt(η5-cyclopentadienyl)]benzyl alcohol

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Technology Process of [α-(η4-tetraphenylcyclobutadiene)cobalt(η5-cyclopentadienyl)]benzyl alcohol

There total 1 articles about [α-(η4-tetraphenylcyclobutadiene)cobalt(η5-cyclopentadienyl)]benzyl alcohol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 36.0%

: 12427-78-0
(η4-tetraphenylcyclobutadiene)(η5-cyclopentadienylcarboxaldehyde)cobalt

: 591-51-5
phenyllithium

: 182627-84-5
[α-(η4-tetraphenylcyclobutadiene)cobalt(η5-cyclopentadienyl)]benzyl alcohol

Guidance literature:: In tetrahydrofuran; under N2; soln. of Co complex in dry THF cooled to -60°C; PhLi added slowly; warmed gradually to 20°C; stirred overnight; quenchedwith water; washed with water; dried; org. layer concd. in vac.; chromd. (alumina, toluene-hexane); second yellow orange band collected; concd.; elem. anal.;
DOI:10.1016/j.jorganchem.2004.02.021

Reference yield:

: 67969-82-8
tetrafluoroboric acid diethyl ether

: 182627-84-5
[α-(η4-tetraphenylcyclobutadiene)cobalt(η5-cyclopentadienyl)]benzyl alcohol

: 710339-35-8
(η4-tetraphenylcyclobutadiene)(η5-C5H4CH(Ph))cobalt(1+)

Guidance literature:: In dichloromethane-d2; under Ar; in NMR tube; soln. of Co complex in CD2Cl2 cooled to -80°C; a drop of HBF4*OEt2 added; not isolated; detd. by (1)H and (13)C NMR spectra;
DOI:10.1016/j.jorganchem.2004.02.021