bis-[(p-dimethylaminobenzyl)cyclopentadienyl]titanium(IV)dichloride

Base Information

• Chemical Name: bis-[(p-dimethylaminobenzyl)cyclopentadienyl]titanium(IV)dichloride
• CAS No.: 870297-95-3
• Molecular Formula: C₂₈H₃₂Cl₂N₂Ti
• Molecular Weight: 515.361
• Mol file: 870297-95-3.mol

Synonyms:

Chemical Property of bis-[(p-dimethylaminobenzyl)cyclopentadienyl]titanium(IV)dichloride

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of bis-[(p-dimethylaminobenzyl)cyclopentadienyl]titanium(IV)dichloride

There total 1 articles about bis-[(p-dimethylaminobenzyl)cyclopentadienyl]titanium(IV)dichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.1%

(p-N,N-dimethylaminobenzyl)cyclopentadienyllithium + titanium tetrachloride (7550-45-0) → bis-[(p-dimethylaminobenzyl)cyclopentadienyl]titanium(IV)dichloride (870297-95-3)

Guidance literature:

In tetrahydrofuran; toluene; byproducts: LiCl; Li org. salt dissolved in THF; soln. of TiCl4 in toluene added dropwise at 0°C; mixt. refluxed for 16 h; soln. cooled; solvent removed (vac.); residue extd. (CH2Cl2); filtered through Celite; filtrate filtered twice; solvent removed (vac.); dried (vac.); elem. anal.;

DOI:10.1016/j.jorganchem.2005.06.039

Reference yield: 66.6%

hydrogenchloride (7647-01-0,15364-23-5) + bis-[(p-dimethylaminobenzyl)cyclopentadienyl]titanium(IV)dichloride (870297-95-3) → bis-[(p-dimethylaminobenzyl)cyclopentadienyl]titanium(IV)dichloride dihydrochloride

Guidance literature:

In diethyl ether; dichloromethane; titanocene dissolved in CH2Cl2; excess of ethereal soln. of HCl added; Et2O added; stirred for 15 min; liq. decanted; powder dried (vac.); elem. anal.;

DOI:10.1016/j.jorganchem.2005.06.039

upstream raw materials:

titanium tetrachloride